2010 Copa Petrobras São Paulo – Doubles

Franco Ferreiro and Ricardo Mello are the defending champions. Mello decided not to participate this year.

Ferreiro competed with André Sá and they won this year's edition after beating Rui Machado and Daniel Muñoz-de la Nava 3–6, 7–6(2), [10–8] in the final.

Seeds
• # 🇧🇷 Franco Ferreiro / 🇧🇷 André Sá (champions)

• # 🇦🇷 Juan Pablo Brzezicki / Leonardo Tavares (withdrew due to Brzezicki's muscle tear injury)

• # Rui Machado / 🇪🇸 Daniel Muñoz-de la Nava (final)

• # 🇧🇷 Rogério Dutra da Silva / 🇧🇷 João Souza (first round)