2014 Monterrey Open – Singles

Anastasia Pavlyuchenkova was the defending champion, but she chose not to participate this year.

Ana Ivanovic won her second title of the year, defeating fellow Serbian Jovana Jakšić 6–2, 6–1 in the final, the first (and to date only) all-Serbian final on the WTA tour.

Seeds
• 🇮🇹 Flavia Pennetta (first round)

• 🇷🇸 Ana Ivanovic (champion)

• Caroline Wozniacki (semifinals)

• 🇧🇪 Kirsten Flipkens (first round)

• 🇪🇸 Garbiñe Muguruza (first round)

• 🇸🇰 Magdaléna Rybáriková (quarterfinals)

• 🇮🇹 Karin Knapp (first round)

• Monica Puig (quarterfinals)

Seeds
• # 🇹🇭 Luksika Kumkhum (qualified)

• # 🇷🇺 Alexandra Panova (first round)

• # 🇨🇦 Aleksandra Wozniak (qualified)

• # 🇻🇪 Adriana Pérez (qualifying competition)

• # 🇺🇸 Sachia Vickery (qualifying competition)

• # 🇪🇪 Anett Kontaveit (first round)

• # 🇨🇦 Gabriela Dabrowski (qualifying competition)

• # 🇫🇷 Amandine Hesse (second round)

Qualifiers
• # 🇹🇭 Luksika Kumkhum

• # 🇺🇸 Julia Boserup

• # 🇨🇦 Aleksandra Wozniak

• # Dalila Jakupovič