2014 Rio Open – Women's doubles

This was the first edition of the event. Irina-Camelia Begu and María Irigoyen won the title, defeating Johanna Larsson and Chanelle Scheepers in the final, 6–2, 6–0.

Seeds
• # 🇨🇿 Barbora Záhlavová-Strýcová / 🇨🇿 Klára Zakopalová (semifinals)

• # Darija Jurak / Andreja Klepač (first round)

• # 🇭🇺 Tímea Babos / 🇦🇺 Jarmila Gajdošová (quarterfinals)

• # 🇺🇦 Irina Buryachok / 🇵🇱 Katarzyna Piter (first round)