Portal:Physics/Selected article/Week 15, 2007

The concept of entropy (Greek: εν (en=inside) + verb: τρέπω (trepo= to chase, escape, rotate, turn)) in thermodynamics is central to the second law of thermodynamics, which deals with physical processes and whether they occur spontaneously. Spontaneous changes occur with an increase in entropy. Spontaneous changes tend to smooth out differences in temperature, pressure, density, and chemical potential that may exist in a system, and entropy is thus a measure of how far this smoothing-out process has progressed. In contrast, the first law of thermodynamics deals with the concept of energy, which is conserved. Entropy change has often been defined as a change to a more disordered state at a molecular level. In recent years, entropy has been interpreted in terms of the "dispersal" of energy. Entropy is an extensive state function that accounts for the effects of irreversibility in thermodynamic systems.

Image: ice melting - classic example of entropy increasing described in 1862 by Rudolf Clausius as an increase in the disgregation of the molecules of the body of ice.