User:Ajmaclaurin/Cubanite

= Cubanite =

Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, cubanite falls between 3.5 and 4 and has a orthorhombic crystal system. Cubanite is chemically similar to chalcopyrite but is the less common copper iron sulfide mineral due to crystallization requirements.

Cubanite occurs in high temperature hydrothermal mineral deposits with pyrrhotite and pentlandite as intergrowths with chalcopyrite. It results from exsolution from chalcopyrite at temperatures below 200 to 210 °C. If cubanite is exposed to temperatures above 210 °C, it will transform into isocubanite. After this transformation, if it begins to cool, it will not revert to cubanite. Upon its transformation to isocubanite it will lose its highly magnetic property due to its change from an orthorhombic to a cubic crystal structure. Cubanite has been identified on chondrites and within stardust and has improved the precision of copper isotope analysis.

Etymology and History
Cubanite comes from the Spanish word Cubano, or Cuban in English, and the suffix -ite, when naming a mineral. Cubanite was first described in 1843 for its occurrence in the the Mayarí-Baracoa Belt, Oriente Province, Cuba. It may also be referenced as barracanite in some literature.

Extraterrestrial Cubanite
Although cubanite forms in hydrothermal mineral deposits, there are occurrences of cubanite that did not form on earth. Cubanite has been found in carbonaceous chondrite meteorites, specifically class CI-chondrites, as well as in cometary samples from NASA’s Stardust spacecraft. Data from the Itokawa asteroid, collected by the Hayabusa spacecraft, indicated that a 2-micrometre grain of cubanite was found on the S-type asteroid. This is the first time cubanite has been found on another asteroid that was not class C-type. However, further inspection of the sample revealed that the cubanite likely formed exogeneous to the Itokawa body.

Synthetic Cubanite
Although synthetic and chondritic cubanite have structural variations, synthesis of cubanite still grants insight into the formation of CI-chondrites. Using a lab-based variant of hydrothermal recrystallization, temperatures between 150-200 °C, and a pH of 9, scientists were able to determine compositions needed to replicate CI-chondrite minerology. Experiments that began with copper + iron + sulfur, covellite + troilite, and copper + sulfur + troilite all formed cubanite. Starting with troilite instead of iron metal reinforces previous studies that sulfides on Cl-chondrites are the resultant of oxidation of troilite by hydrothermal processes.

Copper Isotope Analysis
Due to its complex growth nature, Cubanite has been the test subject for instrumental preference in copper isotope microanalysis. It was found that ultra violet laser ablation multiple collector inductively coupled plasma mass spectrometry (UV-fs-LA-MC-ICP-MS) improves precision in respect to copper isotopes, when compared to the use of near infrared (NIR-fs-LA-MC-ICP-MS) methods.