User:Angela Curry/Sandbox

Early Modern Glass in England
The Early Modern Period or Post-medieval period in England (c. 1500-1800) brought on a revival in local glass production. Medieval glass had been limited to the small scale production of forest glass for window glass and glass vessels, predominantly in the Weald .The organisation of production evolved from small-scale family-run glass houses to large monopolies sanctioned by the crown. The influx of immigrants from Europe brought changes in furnace technology and raw materials, creating a better quality glass. Monastic decrees later banned the use of wood fuel which was then replaced by the less expensive alternative of coal. The development of lead glass in the late 17th century propelled England to the forefront of the glass industry and paved the way for advancements in the Industrial Revolution.

Chemical Composition
Glass has three major components: a network former (silica), a network modifier (flux), and a network stabilizer (predominantly lime). In the early 16th and 17th centuries glassmaking (the manufacture of glass from raw materials) and glassworking (the creation of objects from glass) occurred within the same glasshouse. Glass was also recycled at this time in the form of cullet.

In the Early Modern Era, network formers were obtained from fine or coarse sands which were usually located near the area of production or from silica based pebbles.

Network Modifiers were used to alter the chemical composition of the the network former and reduce the melting temperature of the batch. These fluxes varied depending on the type of glass. Potash (K2O) based alkalis were used extensively in glass production.

The type of flux selected heavily influenced the quality of the glass produced. In England, beech wood and oak were preferred for forest glass. For soda glasses (Na2O), alkalis were often found in the form of marine plants – either local kelp or imported plants from the Mediterranean and the Near East (barilla, polverine, rochetta, sevonus, natron).

Network stabilizers in Early Modern England continued to be lime sources. Lime occurs as a natural contaminant in most sands, and may also be intentionally added to the melt.

Compositional Groups
Five glass compositional groups have been identified through analysis of archaeologically recovered glass from this period. These have been further reduced into two types, ‘green glass’ and ‘white glass’ The groups include:
 * Potash-lime-silica glass (forest or green glass, usually has excess of 10% wt oxide K20
 * High Lime Low Alkali, HLLA (green glass) <10% Na2O,K20, 15-20% CaO
 * Soda-lime glass (white glass/ ‘ordinary glass’) Low MgO, CaO, high K2O
 * Mixed alkali glass (white glass/ crystallo) Na2O K2O and CaO levels low
 * Lead glass (white glass/ façon de venise) 25-35% PbO

The following table represents the mean compositional data derived from the analysis of materials at the Old Broad Street furnace in London (dated to the early 17th Century) and those recovered from Phase Two (circa 1680-1700 AD) Silkstone, Yorkshire. From Dungworth's compilation and analysis Data is represented in wt% oxides and those below the detection limits (0.2% or less) are shown by '-'

Colorants
There are numerous factors that may influence colouration during glass production. These include contamination within raw materials, furnace conditions, and deliberate additives that would provide known colour variations.

Iron existed as a contaminant in sands, producing either a green or brown colour depending upon the oxidation state,. Coal fumes provided a carbon contaminant which could create a dark brown or black colour. Manganese present in wood ash may have contributed to the lighter, translucent green colour. Other trace elements present in alkalis (such as MnO in beech ash) undoubtedly influenced the finished product.

Other metal oxide colorants were known from earlier periods in antiquity.

Early Post Medieval Glass
Glasshouse traditions continued in the Weald from the Medieval period. One such glasshouse has been recovered at Bagot's Park in Staffordshire, which dates from circa 1535 AD, which contained an early melting furnace and smaller annealing furnace. The melting furnace had two siege benches for the placement of three pots each (crucibles) with a central flue cut into the floor to create a draught that would allow the furnace to achieve 1200oC in order to melt the glass. Fritting, and the preheating of crucibles may have occurred in the upper areas of the main furnace. Annealing (glass) and glass blowing probably occurred smaller furnace. A large and small cullet heap were found on either side, suggesting the use of a flux to reduce melting temperatures. Some crushed white pebbles were recovered in the bottom of pots, and this may reflect the silica source used at this site. The glass recovered from Bagot's Park was badly weathered, yet the ends of broad glass and crown glass suggest that window and vessel glass were produced.

Glass Technology
The majority of glass at this time were blown or mould blown into a variety of vessels. This was enhanced by decorative styles, including optic decoration, trailing the glass, or trailing with pre-fabricated glass canes to replicate Venetian traditions.

Influences from the Continent
In 1567, Jean Carré arrived in London from Antwerp and obtained a crown-sanctioned patent for the production of window glass. This patent was awarded to Carré on the condition that prices remained low and that glassmaking and blowing would be taught to native Englishmen to promote the craft. He brought many Venetian craftsmen to his London workshop and opened a second furnace outside the city to produce vessel and green glass.

Later in 1574, Jacob Verzelini, a Venetian who worked for Carré was granted a monopoly over Venetian-style vessel glass. This effectively banned most of the imports from Venice and promoted glass made locally in England. His goal was to produce crystallo glass as well as façon de venise, which he achieved by importing barilla from Spain. This effectively helped to lower the price of glasses and made them available to a wider range of people.

Green glass production remained on a small scale and was made by numerous glasshouses in different areas for local consumption.

Technological Changes
With the new influx of immigrants from the European Continent in the mid 16th century, changes became visible in the quality of glass produced. This was possibly the combined result of experience and the selection/importation of more pure raw materials.

Winged Furnaces
Additionally, glass furnaces constructed at this time began to reflect continental styles. This trend in the archaeological record supports the the evidence for immigrant glassmakers. Wing-like additions were added to the late 16th-early 17th century furnace remains of Hutton and Rosedale in York, two glass producing sites from this period which were located in York, as well as Vann Copse in the Weald. Hutton’s furnace had two wings added in the northeast and southeast corners of the original rectangular melting furnace. A smaller nearby furnace was abandoned around the same time as the addition of the wings, suggesting that they provided an area for either annealing or pre-heating pots.

Rosedale and Vann Copse were in similar styles but with four wings, one in each corner, which were built with the original furnace. The wings had evidence of heating which again suggested these were areas for fritting or glassworking. The glass produced at Rosedale was generally cleaner and of a better quality than that of Hutton although the reasons for this are still unclear. Production at Rosedale appeared to have a higher output than that of Hutton, as two additional smaller furnaces indicate that a larger operation had occurred. It is thought that these furnaces are similar to those of the Lorraine style, and later research in the Netherlands suggests contemporary continental furnaces were made in this fashion.

Change to Coal
From 1581-1584, Parliament became increasingly concerned over the wood supply in the country. At this time, a large number of high temperature industries were dependent on wood for fuel and this began to diminish the country‘s forests. The original decree in this time prohibited the use of wood fuel unless it was from one’s own land. By 1609, Sir Edward Zouch was granted a patent to experiment with coal as the main fuel for a furnace at Winchester and by 1615 Parliament had banned the use of wood fuel.

Adopting coal as the main source of fuel created numerous problems for glass production. Burning coal produced short flames which shifted the location of the hearth from the far ends of the furnace to the center. Air draughts are also necessary to create a regenerative heating system for glassmelting. Early coal furnaces, such as Bolsterstone, contain underground flues to provide an easy way to remove ash. Additionally, the carbon from the coal fumes contaminated the glass in the uncovered pots which created a dark and often uneven colour. Lids, such as those found at Bolsterstone, needed to be implemented to prevent these impurities. Glass bottles from this initial transition are often dark in color.

Charles Mansell
By 1616, Charles Mansell had bought out the patent and company started by Zouch. He began many ventures and set up a successful glasshouse near a coal source in the attempts to save money and to more easily meet the demands of London. His crystallo furnace at Broad Street, London, had faired successfully. Some of his earlier attempts to set up new a furnace to produce glass for the growing needs of London failed, as transportation costs proved to be too high. Yet the furnace Mansell set up at Newcastle was successful

Another winged furnace was set up at Kimmeridge using local sources of oil shale as fuel. Unlike other wing furnaces, the one at this site had deep flues and a centrally located hearth, illustrating the adaption to a new fuel source. This furnace was demolished in 1623 in violation of Mansell’s monopoly.

Conical Furnaces
The conical glasshouses of England of the late 17th century introduced the use of a chimney and a new plan shape to furnaces. This development was possibly drawing off the idea of earlier wind furnaces and the beehive shaped Venetian style furnaces known from historical documents in England. The addition of the chimney created both a strong draught but also doubly acted to extract the coal fumes. The earliest examples appear in Bristol and at Gawber, Yorkshire.

These furnaces had underground flues and chimneys with air holes to provide a strong air draught to control heat. Fritting, pre-heating pots and annealing processes occurred in different sections of the furnace, elevated above the heat source.

The Expansion of the Industry
In 1763, George Ravenscroft developed flint glass, a colourless and translucent glass with many desirable working properties. The original recipe was subject to crizzling. Later batches had the addition of lead oxide (PbO) which combated this problem and produced a superior glass that was more suitable for to engraving and etching. Lead glass was widely adopted by the Glass seller’s guild when Ravenscroft’s patent expired.

Lead glass helped to propel England to the front of the glass industry. Bottles for wine and phials began to be produced and exported on a large scale. The archaeological remains of the Albion shipwreck off Margate in 1765 contained 11 lead glass ingots, which were thought to be meant for trade with China. Although little is known about these materials, it does suggest that lead glass contributed to England's exports. The 19th century brought on new developments with synthetic materials, such as gas fuel. Additionally, continuous melting production with tank furnaces helped mark the end of the Early Modern period and the beginning of the Industrial Revolution.

Vessel Glass
The evolution of vessel glass became more elaborate and specific throughout the Early Modern period. Mirror glass and glass objects also began to be produced on larger scales during the Early Modern period. Types of objects include:


 * Phials
 * Goblets
 * Drinking Glasses
 * Beakers
 * Tankards
 * Jugs
 * Bottles
 * Bowls
 * Jars
 * Urinals
 * Flasks
 * Mirror glass

Window Glass
Window glass was produced throughout the period in small scales in the form of crown glass and broad glass. Broad glass was created by blowing a cylinder of glass which was then cut and flattened. This was predominantly made from green glass throughout the 16th century.

Stained Glass
Stained glass in the earliest part of the Early Modern period was imported into England from France. With the Protestant Reformation in England, ecclesiastic buildings became less elaborate and plain with local window glass frequently used in construtction. .