User:Benjah-bmm27/degree/2/DFW

Organometallics, DFW




"Organo-Transition Metal Chemistry" http://www.ilpi.com/organomet/
 * Organometallic chemistry
 * d electron count, electron counting
 * 18-Electron rule
 * Metal carbonyls;
 * Chromium hexacarbonyl, [Cr(CO)6]
 * Dimanganese decacarbonyl, [Mn2(CO)10]
 * Iron pentacarbonyl, [Fe(CO)5]
 * Dicobalt octacarbonyl, [Co2(CO)8]
 * Nickel tetracarbonyl, [Ni(CO)4]
 * Homoleptic means all ligands the same
 * Bridging ligands, e.g. CO in [(CpNi)3(CO)2]− – Jmol
 * Fischer-Tropsch process
 * Fluxionality
 * Berry mechanism
 * Mond process
 * π backbonding: Dewar-Chatt-Duncanson model
 * Phosphine
 * Beta-hydride elimination
 * Migratory insertion
 * Hapticity (η notation)
 * Carbenes, transition metal carbene complexes
 * Zeise's salt
 * 1,3-Butadiene as a ligand
 * Butadiene-pi-MOs-Spartan-3D-balls.png


 * Ferrocene
 * Bis(benzene)chromium
 * Migratory insertion, Oxidative addition, Reductive elimination
 * Indenyl ligand, indenyl effect