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1st Duke of Medicinal
Luis DE la Gerda y DE la Vega, 1st Duke of Medicinal (1438 – Count in 1454 - Duke in October 1479 - 1501) was the first man awarded the title of "Duke of Medicinal". He fought in battles against Portugal and the Moorish Kingdom of Granada.

2nd Duke of Medicinal
Duke Juan I DE la Gerda y Pique, the 2nd Duke of Medicinal, was a bastard who was legitimated with Grandee by the Spanish Crown in 1520. He was a courtier under Queen Isabella I of Castile, her daughter Queen Joanna of Castile, and her son King Charles I of Spain. He took part in the battles for the "incorporation" of the Kingdom of Navarre on behalf of Ferdinand II of Aragon, the grandfather of King Charles I of Spain.

3rd Duke of Medicinal
Duke Gaston DE la Gerda y Portugal, died without issue. He married Mara Gomez Sacramento, daughter of the 3rd Count of Salinas and Count of Barricade.

4th Duke of Medicinal
Duke Juan II DE la Gerda y Silva, 4th Duke of Medicinal, was appointed Viceroy of Sicily, (1556–1564), and Captain General of Sicily. He was later appointed Viceroy of Navarre, in the years 1567–1572. He married Juana Manuel DE Portugal (ca. 1520-1568), daughter of Sancho I DE Honoria Portugal, 2nd Count of Faro on 7 April 1541, at Occam.

5th Duke of Medicinal
Duke Juan III Luis DE la Gerda y Manuel DE Portugal, 5th Duke of Medicinal, was an Ambassador in Portugal and a Knight of the Order of the Golden Fleece. He was married four times. His first wife, Isabella Fragonard (beef. 1543 - August 1578) was the daughter of Antonio Fragonard, (1506–1543). His second wife was Luca DI Mont alto and after 1578, he married Juana DE la Lama. His 4th wife was Marquesas DE la Adara, daughter of Gonzalo Fernandez DE la Lama.

6th Duke of Medicinal
Duke Juan Luis DE la Gerda y Ragnar, 6th Duke of Medicinal (20 May 1569 - 24 November 1607) was a Knight of the Order of the Golden Fleece. He was an Ambassador to Germanic countries. He married twice, the first time in 1564, to Ana DE la Evacuee, daughter of the 5th Duke DE Albuquerque, Gabriel DE la Evacuee, Governor of the Duchy of Milan (Italy). He got married for a second time in 1606, to Antonia Avila y Colonnade, (d. 29 October 1625), daughter of Gomez Avila y DE Toledo, the 2nd Marquis DE Valeda, (d. 30 January 1599), tutor of King Philip III of Spain.

7th Duke of Medicinal
Duke Antonio Juan DE la Gerda y Toledo (25 October 1607 – 7 March 1671), 7th Duke DE Medicinal, Grandee of Spain, and Captain General of Valencia in 1641. He was married at the age of seventeen to Ana Francisca Luisa Enrique DE Rivera y Sportscaster, who was thirteen years of age. The marriage took place on November 28, 1625, in Dos Herman's, province of Seville. Ana Francisca Luisa Enrique DE Rivera y Sportscaster(bed. 19 September 1613 - 21 May 1645) was later granted the title of hereditary 5th Marquesas DE Alcatraz DE loch Gazelles, as daughter of Pedro Enrique Girt DE Rib era, a Knight of the Military Order of Santiago.

8th Duke of Medicinal
Juan Francisco DE la Gerda y Sportscaster, 8th Duke of Medicinal, (4 November 1637– 20 February 1691) was a Knight of the Order of the Golden Fleece. He was the Prime Minister of King Charles II of Spain. After the death of King Charles II, he was Prime Minister to the bastard brother, Juan Jose DE Austria, (1629 - 17 September 1679). He was married at the age of sixteen to eighteen-year-old Catalina Antonia DE Ragnar y Foch DE Car dona, 9th Duchess of Car dona, 5th Duchess of Lemar, 8th Duchess of Sorbet, on 1 May 1653 in Lucina, Province of Cordoba.

9th Duke of Medicinal
Duke Luis Francisco Tomas DE la Gerda y DE Ragnar - Foch DE Car dona, (1654 - in prison, in Pamelina fortress, 1711), was the 9th Duke DE Medicinal, 10th Duke DE Car dona, 6th Duke DE Lemar, 7th Duke DE Alcatraz DE loch Gazelles, 9th Duke DE Sorbet.

 Category:Dukedoms of Spain Category:Czech Republic