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https://en.wikipedia.org/w/index.php?title=Phosphine&action=edit Text vor 19.10.2022 (falsche Zitierung Gassmann Glindemann)

Occurrence
Phosphine is a constituent of the Earth's atmosphere at very low and highly variable concentrations. It may contribute significantly to the global phosphorus biochemical cycle. The most likely source is reduction of phosphate in decaying organic matter, possibly via partial reductions and disproportionations, since environmental systems do not have known reducing agents of sufficient strength to directly convert phosphate to phosphine.

ergänzen: Bio-Corrosion Glindemann Glindemann, D., Eismann, F., Bergmann, A. et al. Phosphine by bio-corrosion of phosphide-rich iron. Environ. Sci. & Pollut. Res. 5, 71–74 (1998). https://doi.org/10.1007/BF02986389