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The stopped flow methods have limitation, for example, we need to consider about the time it takes to mix gases or solutions and are not suitable if the half-life is less than about a hundredth of a second.

Chemical kinetics." Britannica Academic, Encyclopædia Britannica, 5 Aug. 2019. academic-eb-com.proxy.wexler.hunter.cuny.edu/levels/collegiate/article/chemical-kinetics/126471. Accessed 1 Dec. 2019.