User:MarathonrunnerCU/sandbox

Bismuth antimonides (Bi1-xSbx) are binary compounds of bismuth and antimony in various ratios. They were the first experimentally-observed three-dimensional topological insulators, materials that have conducting surface states but have an insulating interior. They also superconduct at low temperatures, are semiconductors, and are used in thermoelectric devices.

Synthesis
Crystals of bismuth antimonides are synthesized by melting bismuth and antimony together under inert gas or vacuum. Zone melting is used to decrease the concentration of impurities. When synthesizing single crystals of bismuth antimonides, it is important that impurities are removed from the samples, as oxidation occurring at the impurities leads to polycrystalline growth.

Topological Insulator
Pure bismuth is a semimetal, containing a small band gap, which leads to it having a relatively high conductivity (7.7*105 S/m at 20 °C). When the bismuth is doped with antimony, the conduction band decreases in energy and the valence band increases in energy. At an Sb concentration of 4%, the two bands intersect, forming a Dirac point (which is defined as a point where the conduction and valence bands intersect). Further increases in the concentration of antimony result in a band inversion, in which the energy of the valence band becomes greater than that of the conduction band at specific momenta. Between Sb concentrations of 7 and 22%, the bands no longer intersect, and the Bi1-xSbx becomes an inverted-band insulator. It is at these higher concentrations of Sb that the band gap in the surface states vanishes, and the material thus conducts at its surface.

Superconductor
The lowest temperatures at which Bi.4Sb.6 thin film of thicknesses 150-1350A superconduct, the critical temperature Tc, is approximately 2K. Single crystal Bi.935Sb.065 can superconduct at slightly higher temperatures, and at 4.2K, its critical magnetic field Bc (the maximum magnetic field that the superconductor can expel) of 1.6T at 4.2K.

Semiconductor
Electron mobility is one important parameter describing semiconductors because it describes the rate at which electrons can travel through the semiconductor. At 40K, electron mobility ranged from 0.49*106 cm2/Vs at an Sb concentration of 0 to .24*106 cm2/Vs at a Sb concentration of 7.2%. This is much greater than the electron mobility of other common semiconductors like Si, which is 1400 cm2/Vs at room temperature.

Another important parameter is the effective electron mass, a measure of the ratio of the acceleration of an electron to the force applied to an electron. The effective electron mass is .002me for x=.11 and .0009me at x=.06. This is much less the electron effective mass in many common semiconductors (1.09 in Si at 300K, .55 in Ge, and .067 in GaAs).

Thermoelectric
Bismuth antimonides are used as the n-type legs in many thermoelectric devices below room temperature. The thermoelectric efficiency, given by its figure of merit zT = σS2T/λ, where S is the Seebeck coefficient, λ is the thermal conductivity, and σ is the electrical conductivity, describes the ratio of the energy provided by the thermoelectric to the heat absorbed by the device. At 80K, the figure of merit (zT) for Bi1-xSbx peaks at at 6.5*10−3/K when x = 15%. Also, The Seebeck coefficient (the ratio of the potential difference between ends of a material to the temperature difference between the sides) at 80K of Bi.9Sb.1 is -140μV/K, much smaller than the Seebeck coefficient of pure bismuth, -50μV/K.