User:Mpatel/sandbox/Schrödinger equation

In physics, especially quantum mechanics, the Schrödinger equation is an equation that describes how the quantum state of a physical system varies. According to the Copenhagen interpretation of quantum mechanics, the state vector is used to calculate the probability that a physical system is in a given quantum state. Schrödinger's equation is primarily applied to microscopic systems, such as electrons and atoms, but is sometimes applied to macroscopic systems (such as the whole universe). The equation is named after the physicist Erwin Schrödinger who proposed the equation in 1926.

A state vector encodes the probabilities for the outcomes of all possible measurements applied to the system. It contains all information of the system that is knowable in a quantum mechanical sense. As the state of a system generally changes over time, the state vector is a function of time. The Schrödinger equation provides a quantitative description of the rate of change of the state vector.

The Schrödinger equation is commonly written as an operator equation describing how the state vector evolves over time. By specifying the total energy (Hamiltonian) of the quantum system, Schrödinger's equation can be solved, the solutions being quantum states.

The Schrödinger equation is of central importance in non-relativistic quantum mechanics, playing a role for microscopic particles analogous to Newton's second law in classical mechanics for macroscopic particles. Microscopic particles include elementary particles, such as electrons, as well as systems of particles, such as atomic nuclei.

Historical background and development
Although it can't be derived from classical arguments, a heuristic derivation of Schrödinger's equation follows very naturally from earlier developments:

Heuristic derivation

Assumptions:


 * The total energy of a particle is


 * $$E=\frac{p^2}{2m}+V$$


 * Einstein's hypothesis:


 * $$E = h f\;$$ where the energy E and frequency f of the quanta of radiation (photons) are related by Planck's constant h.


 * The de Broglie hypothesis:


 * $$p=h / \lambda\;$$, where $$\lambda\,$$ is the wavelength of the wave and p the momentum of the particle. This hypothesis also requires:


 * The association of a wave (with wavefunction $$\psi$$) with any particle.

Expressed in terms of angular frequency $$\omega = 2\pi f\;$$ and wavenumber $$k = 2\pi / \lambda\;$$, with $$\hbar = h / 2 \pi\;$$ we get:
 * $$E=\hbar \omega$$

and
 * $$\mathbf{p}=\hbar \mathbf{k}\;$$

where we have expressed p and k as vectors.

Schrödinger's great insight, late in 1925, was to express the phase of a plane wave as a complex phase factor:
 * $$\psi \approx e^{i(\mathbf{k}\cdot\mathbf{x}- \omega t)}$$

and to realize that since
 * $$ \frac{\partial}{\partial t} \psi = -i\omega \psi $$

then
 * $$ E \psi = \hbar \omega \psi = i\hbar\frac{\partial}{\partial t} \psi $$

and similarly since:
 * $$ \frac{\partial}{\partial x} \psi = i k_x \psi $$

then
 * $$ p_x \psi = \hbar k_x \psi = -i\hbar\frac{\partial}{\partial x} \psi $$

and hence:
 * $$ p_x^2 \psi = -\hbar^2\frac{\partial^2}{\partial x^2} \psi $$

so that, again for a plane wave, he got:
 * $$ p^2 \psi = (p_x^2 + p_y^2 + p_z^2) \psi = -\hbar^2\left(\frac{\partial^2}{\partial x^2} + \frac{\partial^2}{\partial y^2} + \frac{\partial^2}{\partial z^2}\right) \psi = -\hbar^2\nabla^2 \psi $$

And by inserting these expressions into the Newtonian formula for a particle with total energy E, mass m, moving in a potential V:
 * $$E=\frac{p^2}{2m}+V$$ (simply the sum of the kinetic energy and potential energy; the plane wave model assumed V = 0)

he got his famed equation for a single particle in the 3-dimensional case in the presence of a potential:
 * $$i\hbar\frac{\partial}{\partial t}\psi=-\frac{\hbar^2}{2m}\nabla^2\psi + V\psi$$

Using this equation, Schrödinger computed the spectral lines for hydrogen by treating a hydrogen atom's single negatively charged electron as a wave, $$\psi\;$$, moving in a potential well, V, created by the positively charged proton. This computation tallied with experiment, the Bohr model and also the results of Werner Heisenberg's matrix mechanics - but without having to introduce Heisenberg's concept of non-commuting observables. Schrödinger published his wave equation and the spectral analysis of hydrogen in a series of four papers in 1926.

The Schrödinger equation defines the behaviour of $$\psi\;$$, but does not interpret what $$\psi\;$$ is. Schrödinger tried unsuccessfully to interpret it as a charge density. In 1926 Max Born, just a few days after Schrödinger's fourth and final paper was published, successfully interpreted $$\psi\;$$ as a probability amplitude, although Schrödinger was never reconciled to this statistical or probabilistic approach.

Mathematical forms
There are various ways of writing Schrödinger's equation, depending on the precise mathematical framework used and whether the wavefunction varies over time.

Time-dependent Schrödinger equation
The time-dependent Schrödinger equation for a system with total energy $$\hat H$$ is:



\hat H \psi\left(\mathbf{r}, t\right) = i \hbar \frac{\partial \psi}{\partial t} \left(\mathbf{r}, t\right) $$

where $$\psi$$ is the wavefunction, $$\hbar$$ is Planck's constant and $$i$$ is the imaginary unit. An abuse of notation has been used in writing the equation in the above operator form (see below). As with the force occurring in Newton's second law, the form of the Hamiltonian is not provided by the Schrödinger equation, but must be independently determined from the physical properties of the system.

As a standard example, a non-relativistic particle with no electric charge and zero spin has a Hamiltonian which is the sum of the kinetic (T) and potential (U) energies :


 * $$\hat H = \left(T + U\right) \ = - \frac{\hbar^2}{2m} \nabla^2 + U\left(\mathbf{r}\right) $$

The Schrödinger equation can then be written explicitly as a partial differential equation


 * $$ -\frac{\hbar^2}{2 m} \left[\frac{\partial^2 \psi}{\partial x^2} + \frac{\partial^2 \psi}{\partial y^2} + \frac{\partial^2 \psi}{\partial z^2} \right] + U \psi = i \hbar \frac{\partial \psi}{\partial t} $$

where the dependence of $$\psi$$ on the space and time coordinates has been suppressed for clarity.

Time-independent Schrödinger equation
For many real-world problems the Hamiltonian does not depend on time. Denoting this constant energy by $$E$$ results in the time-independent Schrödinger equation


 * $$\hat H \psi = E \psi \,$$

An alternative way of saying this is that $$\psi$$ is an eigenstate (eigenket) of $$\hat H$$ with eigenvalue $$E$$. Together with Schrödinger's equation in operator form, this gives,


 * $$ i \hbar \frac{\partial \psi}{\partial t} = E \psi $$

This can be solved for $$\psi$$ as


 * $$\psi\left(\mathbf{r}, t\right) = \phi\left(\mathbf{r}\right) e^{-iEt/\hbar}$$

For such a solution the time-dependent Schrödinger equation simplifies to the time-independent Schrödinger equation:

An example of a simple one-dimensional time-independent Schrödinger equation for a particle of mass m, moving in a potential U(x) is:
 * $$ -\frac{\hbar^2}{2 m} \frac{d^2 \phi (x)}{dx^2} + U(x) \phi (x) = E \phi (x). $$

The analogous 3-dimensional time-independent equation is, :
 * $$ \left[-\frac{\hbar^2}{2 m} \nabla^2 + U(\mathbf{r}) \right] \phi (\mathbf{r}) = E \phi (\mathbf{r}), $$

where $$\nabla^2$$ is the Laplace operator.

Bra-ket versions
In the mathematical formulation of quantum mechanics, a physical system is associated with a complex Hilbert space such that each instantaneous state of the system is described by a ray in that space. The nonzero elements of a Hilbert space are by definition normalizable and it is convenient, although not necessary, to represent a state by an element of the ray which is normalized to unity. This vector is often somewhat loosely referred to as a wavefunction, although in a more rigorous formulation of quantum mechanics a wavefunction is a special case of a state vector. (In fact, a wavefunction is a state in the position representation, see below).

In Dirac's bra-ket notation at time $$t$$ the state is given by the ket $$|\psi(t)\rangle$$. The time-dependent Schrödinger equation, giving the time evolution of the ket, is:


 * $$\hat H(t)\left|\psi\left(t\right)\right\rangle = \mathrm{i}\hbar \frac{d}{d t} \left| \psi \left(t\right) \right\rangle$$

where $$\mathrm{i}$$ is the imaginary unit, $$t$$ is time, $$d/d t$$ is the derivative with respect to $$t$$, $$\hbar$$ is the reduced Planck's constant (Planck's constant divided by $$2\pi\,$$), $$\psi(t)\,$$ is the time dependent state vector, and $$H(t)$$ is the Hamiltonian (a self-adjoint operator acting on the state space). If one assumes a certain representation for $$\psi\,$$, for instance position or momentum representation, the state vector is assumed to depend on more variables than time alone, and the time derivative must be replaced by the partial derivative $$\partial / \partial t. $$

For every time-independent Hamiltonian operator, $$\hat H$$, there exists a set of quantum states, $$\left|\psi_n\right\rang$$, known as energy eigenstates, and corresponding real numbers $$E_n$$ satisfying the eigenvalue equation,


 * $$ \hat H \left|\psi_n\right\rang = E_n \left|\psi_n \right\rang. $$

Such a state possesses a definite total energy, whose value $$E_n$$ is the eigenvalue of the Hamiltonian. The corresponding eigenvector $$\psi_n\,$$ is normalizable to unity. This eigenvalue equation is referred to as the time-independent Schrödinger equation. We purposely left out the variable(s) on which the wavefunction $$\psi_n\,$$ depends. In the first example above it depends on the single variable x and in the second on x, y, and z&mdash;the components of the vector r. In both cases the Schrödinger equation has the same appearance, but its Hamilton operator is defined on different function (state, Hilbert) spaces. In the first example the function space consists of functions of one variable and in the second example the function space consists of functions of three variables.

Self-adjoint operators, such as the Hamiltonian, have the property that their eigenvalues are always real numbers, as we would expect, since the energy is a physically observable quantity. Sometimes more than one linearly independent state vector correspond to the same energy $$E_n$$. If the maximum number of linearly independent eigenvectors corresponding to $$E_n$$ equals k, we say that the energy level $$E_n$$ is k-fold degenerate. When k=1 the energy level is called non-degenerate.

On inserting a solution of the time-independent Schrödinger equation into the full Schrödinger equation, we get


 * $$\mathrm{i} \hbar \frac{\partial}{\partial t} \left| \psi_n \left(t\right) \right\rangle = E_n \left|\psi_n\left(t\right)\right\rang. $$

It is relatively easy to solve this equation. One finds that the energy eigenstates (i.e., solutions of the time-independent Schrödinger equation) change as a function of time only trivially, namely, only by a complex phase:


 * $$ \left| \psi \left(t\right) \right\rangle = \mathrm{e}^{-\mathrm{i} Et / \hbar} \left|\psi\left(0\right)\right\rang. $$

It immediately follows that the probability amplitude,
 * $$\psi(t)^*\psi(t) = \mathrm{e}^{\mathrm{i} Et / \hbar}\mathrm{e}^{-\mathrm{i} Et / \hbar}

\psi(0)^*\psi(0) = |\psi(0)|^2, $$ is time-independent. Because of a similar cancellation of phase factors in bra and ket, all average (expectation) values of time-independent observables (physical quantities) computed from $$\psi(t)\,$$ are  time-independent.

Energy eigenstates are convenient to work with because they form a complete set of states. That is, the eigenvectors $$ \left\{\left|n\right\rang\right\} $$ form a basis for the state space. We introduced here the short-hand notation $$|\,n\,\rang = \psi_n$$. Then any state vector that is a solution of the time-dependent Schrödinger equation (with a time-independent $$ \hat H$$) $$ \left|\psi\left(t\right)\right\rang $$ can be written as a linear superposition of energy eigenstates:


 * $$\left|\psi\left(t\right)\right\rang = \sum_n c_n(t) \left|n\right\rang \quad,\quad \hat H \left|n\right\rang = E_n \left|n\right\rang \quad,\quad \sum_n \left|c_n\left(t\right)\right|^2 = 1.$$

(The last equation enforces the requirement that $$ \left|\psi\left(t\right)\right\rang $$, like all state vectors, may be normalized to a unit vector.) Applying the Hamiltonian operator to each side of the first equation, the time-dependent Schrödinger equation in the left-hand side and using the fact that the energy basis vectors are by definition linearly independent, we readily obtain


 * $$\mathrm{i}\hbar \frac{\partial c_n}{\partial t} = E_n c_n\left(t\right).$$

Therefore, if we know the decomposition of $$ \left|\psi\left(t\right)\right\rang $$ into the energy basis at time $$t = 0$$, its value at any subsequent time is given simply by


 * $$\left|\psi\left(t\right)\right\rang = \sum_n \mathrm{e}^{-\mathrm{i}E_nt/\hbar} c_n\left(0\right) \left|n\right\rang. $$

Note that when some values $$c_n(0)\,$$ are not equal to zero for differing energy values $$E_n\,$$, the left-hand side is not an eigenvector of the energy operator $$ \hat H$$. The left-hand is an eigenvector when the only $$c_n(0)\,$$-values not equal to zero belong the same energy, so that $$\mathrm{e}^{-\mathrm{i}E_nt/\hbar}$$ can be factored out. In many real-world application this is the case and the state vector $$\psi(t)\,$$ (containing time only in its phase factor) is then a solution of the time-independent Schrödinger equation.

Example

Let $$|\,1\,\rangle$$ and $$|\,2\,\rangle$$ be degenerate eigenstates of the time-independent Hamiltonian $$\hat H\,$$:

\hat H\,|\,1\,\rangle = E |\,1\,\rangle \quad \hbox{and} \quad \hat H\,|\,2\,\rangle = E |\,2\,\rangle. $$ Suppose a solution $$\psi(t)\,$$ of the full (time-dependent) Schrödinger equation of $$\hat H\,$$ has the form at t = 0:

c_1 |\,1\,\rangle + c_2 |\,2\,\rangle. $$ Hence, because of the discussion above, at t > 0 :
 * \,\psi(0)\,\rangle =

\mathrm{e}^{-\mathrm{i}Et/\hbar} c_1 |\,1\,\rangle + \mathrm{e}^{-\mathrm{i}Et/\hbar} c_2 |\,2\,\rangle = \mathrm{e}^{-\mathrm{i}Et/\hbar} \left( c_1 |\,1\,\rangle + c_2 |\,2\,\rangle\right) = \mathrm{e}^{-\mathrm{i}Et/\hbar}|\,\psi(0)\,\rangle, $$ which shows that $$\psi(t)\,$$ only depends on time in a trivial way (through its phase), also in the case of degeneracy.
 * \,\psi(t)\,\rangle =

Apply now $$\hat H\,$$:

\hat H\,|\,\psi(t)\,\rangle = \mathrm{e}^{-\mathrm{i}Et/\hbar} c_1 E\,|\,1\,\rangle + \mathrm{e}^{-\mathrm{i}Et/\hbar} c_2 E\, |\,2\,\rangle = E\mathrm{e}^{-\mathrm{i}Et/\hbar} \left( c_1 |\,1\,\rangle + c_2 |\,2\,\rangle\right) $$



= E \mathrm{e}^{-\mathrm{i}Et/\hbar}|\,\psi(0)\,\rangle = E\,|\,\psi(t)\,\rangle. $$ Conclusion: The wavefunction $$\psi(t)\,$$ with the given initial condition (its form at t = 0), remains a solution of the time-independent Schrödinger equation $$\hat H\psi(t) = E\psi(t)$$ for all times t > 0.

Schrödinger wave equation
The state space of certain quantum systems can be spanned with a position basis. In this situation, the Schrödinger equation may be conveniently reformulated as a partial differential equation for a wavefunction, a complex scalar field that depends on position as well as time. This form of the Schrödinger equation is referred to as the Schrödinger wave equation.

Elements of the position basis are called position eigenstates. We will consider only a single-particle system, for which each position eigenstate may be denoted by $$ \left|\mathbf{r}\right\rang $$, where the label $$\mathbf{r}$$ is a real vector. This is to be interpreted as a state in which the particle is localized at position $$\mathbf{r}$$. In this case, the state space is the space of all square-integrable complex functions.

The wave function
We define the wave function as the projection of the state vector $$ \left|\psi\left(t\right)\right\rang $$ onto the position basis:


 * $$\psi\left(\mathbf{r}, t\right) \equiv \left\langle \mathbf{r} | \psi\left(t\right) \right\rangle. $$

Since the position eigenstates form a basis for the state space, the integral over all projection operators is the identity operator:


 * $$\int \left|\mathbf{r}\right\rangle \left\langle \mathbf{r} \right| \mathrm{d}^3 \mathbf{r} = \mathbf{I}.$$

This statement is called the resolution of the identity. With this, and the fact that kets have unit norm, we can show that where $$\psi\left(\mathbf{r}, t\right)^*$$ denotes the complex conjugate of $$\psi\left(\mathbf{r}, t\right)$$. This important result tells us that the absolute square of the wave function, integrated over all space, must be equal to 1:


 * $$ \int \; \left|\psi\left(\mathbf{r}, t\right)\right|^2 \; \mathrm{d}^3\mathbf{r} = 1. $$

We can thus interpret the absolute square of the wave function as the probability density for the particle to be found at each point in space. In other words, $$\left|\psi\left(\mathbf{r}, t\right)\right|^2 \mathrm{d}^3\mathbf{r}$$ is the probability, at time $$t$$, of finding the particle in the infinitesimal region of volume $$\mathrm{d}^3\mathbf{r}$$ surrounding the position $$\mathbf{r}$$.

We have previously shown that energy eigenstates vary only by a complex phase as time progresses. Therefore, the absolute square of their wave functions do not change with time. Energy eigenstates thus correspond to static probability distributions.

Operators in the position basis
Any operator $$A$$ acting on the wave function is defined in the position basis by


 * $$A \psi\left(\mathbf{r}, t\right) \equiv \left\lang\mathbf{r}| A | \psi\left(t\right) \right\rang. $$

The operators A on the two sides of the equation are different things: the one on the right acts on kets, whereas the one on the left acts on scalar fields. It is common to use the same symbols to denote operators acting on kets and their projections onto a basis. Usually, the kind of operator to which one is referring is apparent from the context, but this is a possible source of confusion.

Using the position-basis notation, the Schrödinger equation can be written as


 * $$H \psi\left(\mathbf{r},t\right) = \mathrm{i} \hbar \frac{\partial}{\partial t} \psi\left(\mathbf{r},t\right). $$

This form of the Schrödinger equation is the Schrödinger wave equation. It may appear that this is an ordinary differential equation, but in fact the Hamiltonian operator typically includes partial derivatives with respect to the position variable $$\mathbf{r}$$. This usually leaves us with a difficult linear partial differential equation to solve.

Linearity
The Schrödinger equation (in any form) is linear in the wavefunction, meaning that if $$\psi(x, t)$$ and $$\phi(x,t)$$ are solutions, then so is $$ a \psi \pm b \phi$$. This property of the Schrödinger equation has important consequences.

Linearity of the Schrödinger equation

Assumptions:


 * The Schrödinger equation:


 * $$\hat H(t)\left|\psi(t)\right\rangle = i\hbar \frac{d}{d t} \left| \psi(t) \right\rangle$$


 * $$|\psi\rangle$$ and $$|\phi\rangle$$ are solutions of the Schrödinger equation.


 * $$\hat H(t)\left|a\psi(t) \pm b\phi(t)\right\rangle$$
 * $$=\hat H(t)\left|a\psi(t)\right\rangle \pm \hat H(t)\left|b\phi(t)\right\rangle$$ (as the Hamiltonian is a linear operator)
 * $$= a \left( \hat H(t)\left|\psi(t)\right\rangle \right) \pm b \left( \hat H(t)\left|\phi(t)\right\rangle \right)$$
 * $$=a \left( i\hbar \frac{d}{d t} \left| \psi(t) \right\rangle \right) \pm b \left( i\hbar \frac{d}{d t} \left| \phi(t) \right\rangle \right)$$
 * $$= i \hbar \left( \frac{d}{d t} \left| a\psi(t) \right\rangle \right) \pm i \hbar \left( \frac{d}{d t} \left| b\phi(t) \right\rangle \right)$$
 * $$= i \hbar \frac{d}{d t} \left| a\psi(t) \pm b\phi(t) \right\rangle$$

Conservation of probability
In order to describe how probability density changes with time, it is acceptable to define probability current or probability flux. The probability flux represents a flowing of probability across space.

For example, consider a Gaussian probability curve centered around $$x_0$$ with $$x_0$$ moving at speed $$v$$ to the right. One may say that the probability is flowing toward right, i.e., there is a probability flux directed to the right.

The probability flux $$\mathbf{j}$$ is defined as:


 * $$ \mathbf{j} = {\hbar \over m} \cdot {1 \over {2 \mathrm{i}}} \left( \psi ^{*} \nabla \psi - \psi \nabla \psi^{*} \right)  = {\hbar \over m} \operatorname{Im} \left( \psi ^{*} \nabla \psi \right) $$

and measured in units of (probability)/(area &times; time) = r&minus;2t&minus;1.

The probability flux satisfies a quantum continuity equation, i.e.:


 * $${ \partial \over \partial t} P\left(x,t\right) + \nabla \cdot \mathbf{j} = 0 $$

where $$P\left(x, t\right)$$ is the probability density and measured in units of (probability)/(volume) = r&minus;3. This equation is the mathematical equivalent of probability conservation law.

It is easy to show that for a plane wave,


 * $$ \psi (x,t) = A e^{ \mathrm{i} k x} e^{ - \mathrm{i} \omega t}$$

the probability flux is given by


 * $$ j\left(x,t\right) = \left|A\right|^2 {k \hbar \over m}.$$

Correspondence principle
The Schrödinger equation satisfies the correspondence principle.

Solutions
Analytical solutions of the time-independent Schrödinger equation can be obtained for a variety of relatively simple conditions. These solutions provide insight into the nature of quantum phenomena and sometimes provide a reasonable approximation of the behavior of more complex systems (e.g., in statistical mechanics, molecular vibrations are often approximated as harmonic oscillators). Several of the more common analytical solutions can be found in the list of quantum mechanical systems with analytical solutions.

For many systems, however, there is no analytic solution to the Schrödinger equation. In these cases, one must resort to approximate solutions. Some of the common techniques are:
 * Perturbation theory
 * The variational principle underpins many approximate methods (like the popular Hartree-Fock method which is the basis of the post Hartree-Fock methods)
 * Quantum Monte Carlo methods
 * Density functional theory
 * The WKB approximation
 * Discrete delta-potential method

Free particle Schrödinger equation
An important form of the Schrödinger equation results when the potential function for a single particle is zero:


 * $$i\hbar\frac{\partial \psi}{\partial t}=-\frac{\hbar^2}{2m}\nabla^2\psi $$

The wave function can then be shown to satisfy,


 * $$\psi(x,t)= \, Ae^{i(kx- \omega t)}$$

Relativistic generalisations
The Schrödinger equation as presented so far in this article does not take into account relativistic effects. Generalisations incorporating ideas from special relativity include the Klein-Gordon equation and the Dirac equation.