User:OrganoMetallurgy/Drafts/

This is where I keep my list of topics for articles that I want to be made. (Note that I haven't always checked to make sure they don't exist yet.) '''If you are interested in making or helping to make any of these pages, please let me know. Either here or on my talk page.'''

To do (and how to do it)
I should work more on my drafts. Trying to work on one draft at a time and trying to sticking to it for at least a day (or until I get too frustrated to continue working on the particular draft), should help me stay focused (and productive) and not get overwhelmed like I sometimes due when I work one more that one at a time. I should close the tabs in my browser related to other topics, then I should look for sources on the topic and open them in new tabs, then chose the best sources, then pick relevant pieces of information and add them to the draft along with their citations, then I should organize the information into different sections, then I should string the information into proper(ish) sentences. Then I should ask ask another user to look it over, then I should move it to the main namespace, and add it to any suitable catagories, then I should add links to it from other pages when appropriate. Then I should upload a preliminary image to demonstrate the structure of the compound if there aren't any good images already available in wikimedia, then I should ask someone with access to better drawing tools to create a better image/better images for the article, especially for creating diagrams.

Currently/imminently working on
Applying Wikipedia:Manual of Style/Chemistry to my drafts. (I really should have looked at it earlier) Probably going to be too busy to do anything more extensive than adding or changing a few words at a time for the next couple weeks/months.

Crystal structure types

 * Pyrochlore (structure)
 * Delafossite (structure)
 * Spinel (structure)
 * Rutile (structure)
 * α-NaFeO2 (structure)
 * Rock-salt (structure)
 * Bixbyite (structure)
 * BiF3
 * CaCu5
 * ThCr2Si2
 * HfCuSi2
 * BaAl4
 * K2NiF4
 * ZrCuSiAs
 * NaZn13
 * Cu2Sb
 * Cu3Au

Organic molecules

 * Nitro(pentafluorosulfonyl)benzene more easily synthesis building blocks containing the pentafluorosulfanyl group
 * Phenalenone
 * 9-Hydroxyphenalenone interesting intramolecular hydrogen bond
 * Tetrathionaphthalene
 * Benzenehexathiol, some interesting complexes involving its hexaanion have been made
 * Tetrachlorocyclopentadienone precursor to some pesticides
 * Dithiolium two aromatic organic cations with the formula C3H3S2+
 * Bacterioruberin is a C50 carotenoid found in some extremely halophilic archaea and bacteria.
 * Methanedisulfonic acid. The simplest disulfonic acid.
 * tert-Butyl hypochlorite. An oxidizing agent
 * Dithiadiazolyl, class of radicals
 * Verdazyl radicals. A family of air and water stable radical
 * Perimidine
 * Benzo[1,2-c;4,5-c′]bis[1,2,5]thiadiazole, open shell, molecular conductor stuff, near infrared stuff.
 * Thieno[3,4-c]thiophene
 * Squaramides
 * TEMPO-H, 1-hydroxy-2,2,6,6-tetramethylpiperidine
 * Quinhydrone, a 1:1 cocrystal of benzoquinone and hydroquinone, deep color,
 * Isoindigo
 * Parabanic acid
 * Tetrakis(dimethylamino)ethylene
 * Thienoacene a class of heteroacenes
 * Ketocyanine dyes
 * Oxonol dyes

Hydrocarbons

 * Trannulene is short for "all-trans annulene"
 * [2.2]Paracyclophane strained molecule with bent benzene rings
 * Centrohexaindane has an interesting structure
 * Trishomocyclopropenyl (3-bicyclo[3.1.0]hexyl) cation has a nonclassical structure with a 3 center 2 electron bond, and is trishomoaromatic
 * Cyclopropabenzene, a strained benzene derivative. I'm not sure it exists, but there's been studies using computational chemistry.
 * Decacyclene
 * Indacene(s) s-Indacene also probably as-indacene as well
 * Pleiadene
 * Rubicene
 * Truxene
 * Trindene
 * Pyracylene
 * Azupyrene
 * Hexacyanobenzene, strong electron acceptor
 * Oxonol dyes, polymethine with ketone and olate groups at the ends

Organometallic and metalorganic compounds/complexes

 * Cycloheptatrienyl complexes
 * Ferrochloroquine, an anti-malarial drug with ferrocene in its structure
 * Tris(cyclopentadienyl)dinickel cation, First triple decker sandwich complex. Maybe also expand the section on multidecker sandwich compounds in the article sandwich compound
 * [Ni(chxn)2Br]Br2
 * Cymantrene, cyclopentadienylmanganese tricarbonyl
 * Tetrakis(trifluoromethyl)cuprate(III) anion — a quite stable organocuprate(III)
 * [Ga84{N(SiMe3)2}20-Li6Br2(thf)20]· 2 toluene – consists of isolated subvalent gallium clusters, and exibits superconductivity at low temperatures (~3-4 K).

Inorganic compounds
Cu3VS4 Sulvanite, potential semiconductor material along with other isostructural compounds.
 * Ca(NH3)6
 * Potassium graphite is a graphite intercalation compound that is used as a powerful reducing agent
 * Platinides, compounds with platinum anions.
 * Aurides, compounds with gold anions.
 * Alanes, aluminum hydrides. Or maybe just an article about subvalent aluminum compounds. Often don't follow Wade−Mingos rules.
 * Layered zirconium(hafnium) nitride halides Zr(Hf)NX form superconductive intercalation compounds.
 * CaKFe4As4, a stochiometric iron based superconductor with a high Tc that lacks the disorder associated with doping. Also there's a family of related compounds.
 * CuInP2S6 has a lamellar structure and is ferrielectric with two sublattices and colinear dipoles with a TC of 315 K 10.1103/PhysRevB.56.10860
 * GaV4S8 Multiferroic
 * Ca2N is a 2D electride
 * Sr2N another 2D electride
 * Y2C another 2D electride
 * MnSi, manganese silicide, non-fermi liquid, helical spin structure, other stuff.
 * FeCrAs, non-fermi liquid
 * TaAs, Weyl semimetal
 * ZrTe5, Dirac semimetal
 * YNi2B2C superconductor
 * Cs2SbCl6, Dicesium hexachloroantimonate(III,V), blue due to charge transfer transition, mixed valence main group compound.
 * PbTaSe2 and other tin and lead intercalation compounds of tantalum and niobium dichalcogenides.
 * other intercalation compounds of tantalum and niobium dichalcogenides
 * NbS2
 * Trithiazyl trichloride S3N3Cl3
 * LiFeAs a superconductor
 * MnPS3 or Mn2P2S6 – intercalation host, 2D magnetic ordering?
 * Ta2NiSe5, probable excitonic insulator.
 * BaNiS2 and BaCoS2 and their solid solutions. Metal insulator transition, other stuff.
 * Li@C60 Has been synthesized and isolated in reasonable amounts, maybe focus on salts of the cation? Like [Li+@C60]PF6–
 * AgSO4 Silver(II) sulfate. Divalent silver.
 * Ta2S2C tantalum carbide sulfide.

Zintl phases and related (might not all warrant separate articles)

 * K4Ge9 Contains the deltahedral Zintl Ge94– anion.
 * K4Sn9 Contains the deltahedral Zintl Sn94– anion.
 * K4Pb9 Contains the deltahedral Zintl Pb94– anion.

Zintl ions

 * Pb94–
 * Sn94–
 * Ge94–
 * Pb93–
 * Sn93–
 * Ge93–
 * Pb102–
 * Pb52–
 * Sn52–
 * Ge52–
 * As73–
 * As113–
 * Sb73–
 * Sb113–
 * Sb42–
 * Bi42–

Oxides

 * Various other oxides with spinel, perovskite, or pyrochlore structures that have interesting properties.
 * Maybe a list of compounds with a perovskite structure
 * Silver oxide clathrates of the type Ag7O8X
 * YMnO3 is a multiferroic material, it's both ferroelectric and antiferromagnetic.
 * LuFe2O4 Multiferroic
 * Eu rich EuO undergoes a inverse metal insulator transition at low temperatures that's associated with its magnetic structure
 * Ag13OsO6, might not be notable (judging by the number of things published about it), but it's a pretty neat, subvalent silver compound.
 * Ag5Pb2O6 Subvalent silver.
 * Ag2NiO2 Subvalent silver. Ag2MnO2 and Ag2CrO2 are also known.
 * Clathrasil(s) a family of silica clathrates?
 * LiOsO3 a sort of ferroelectric metal.

Spinels

 * LiTi2O4 Is the only known oxide superconductor with a spinel structure
 * AlV2O4 Interesting charge ordering, formation of "molecules"
 * MgTi2O4
 * LiV2O4 exhibits heavy fermion behavior which is uncommon among compounds without f-block elements.

Perovskites

 * PbNiO3
 * SrRuO3 Non-fermi liquid.
 * CaFeO3 Charge disproportionation.
 * SrFeO3
 * LaFeO3
 * LaNiO3
 * LaCoO3 Spin state transitions
 * LaCrO3
 * LaVO3
 * LaTiO3
 * LaMnO3
 * EuTiO3
 * BiAlO3

Delafossites

 * Delafossite(s). An article of compounds with the delafossite structure would be nice. Lots of interesting stuff regarding some compounds with a delafossite structure. Transparent p-type conductors, potential superconductivity, weird magnetic ordering, ect.
 * PdCoO2 A metallic compound with a delafossite structure that has extremely low in-plane resistivity and extremely large magnetoresistance among other remarkable properties.
 * CuCrO2
 * CuAlO2
 * CuFeO2
 * AgNiO2 Weird charge order, high conductivity compared to other silver containing delafossites.

Pyrochlores

 * Cd2Re2O7
 * Tl2Mn2O7 Colossal Magnetoresistance

Cuprates

 * NaCuO2
 * La2CuO4
 * Nd2CuO4
 * Ca2CuO2Cl2
 * Sr2CuO2Cl2
 * Ruthenocuprates coexisting superconductivity and magnetism
 * FeSr2YCu2O6+δ An iron containing superconductive cuprate.

Halides

 * KCuF3 Is a perovskite that has interesting magnetic exchange interations (ferromagnetic coupling due to antiferroorbital ordering)
 * The structure of K2NiF4 is a structure prototype
 * K3Fe5F15 And related materials with tetragonal tungsten bronze structures.
 * KAgF3 Divalent silver, quasi-1D magnetism, metallic conductivity.
 * Cs2AgF4 Divalent silver, ferromagnetic exchange, orbital ordering.
 * CaZrF6 Has large isotropic negative thermal expansion. Has a double ReO3 structure.

Boranes and related salts/anions

 * B12H10(CO)2
 * Macropolyhedral borane(s)
 * B20H16
 * (Sodium) Octahydrotriborate
 * B21H18 anion, face fused derivative of B12H12 dianion
 * B12Me12 dianion can be reduced to radical monoanion
 * nido-Undecaborane, B11H15 Not very stable. Probably better to do one on the B11H14- anion which is considerably more stable and generally more notable
 * Boron subhalides. Some known boron subchlorides are B2Cl4, B4Cl4, B8Cl8, B9Cl9
 * B4R4 either tetrahedral or open

Heteroboranes and related salts/anions

 * m-Carborane
 * closo-Azadodecaborane, NB11H12
 * Silaborane(s)
 * Thiaborane(s)
 * Phosphaborane(s)
 * C4B2H6 is a nido carborane with a pentagonal pyramid. The peralkylated derivates are more stable.
 * Dicarbadecaborane, formula C2B8H*0. bicapped square antiprism
 * CB11H12 anion, icosahedral geometry. Weakly coordinating anions.
 * C2B11H13 a supraicosahedral carborane (well I don't think it's known but C-substituted derivatives are known)

Functional groups/Ligands

 * Tris(trimethylsilyl)methyl aka trisyl, a very bulky alkyl ligand/functional group. Do it on the lithium derivative
 * Neopentyl, has some interesting properties, such as slow nucleophilic substitution, steric effect, and stability against beta hydride elimination since it has no beta hydrogens
 * The tert-butyl group probably deserves its own page instead of just being lumped together with the other butyl groups on the page Butyl group.

Other topics

 * Extrusion reactions
 * Reentrant phase transition is a phase transition involving the return to a previous phase. An example of is rochelle salt, a ferroelectric, which has two curie points and returns to a paraelectric phase below its lower curie point.
 * Non-nuclear maxima (electron density) are, as the name suggests, maxima of electron density that aren't associated with an atomic nucleus, unlike is typically the case). The simplest molecule exhibiting one is Li2 where there is a non nuclear maxima located at the midpoint between the two lithium nuclei. A closely related concept is non-nuclear attractor.
 * Pancake bond. Face to face multicenter bonds. 10.1016/j.poly.2014.04.005 is a potential source.
 * σ-hole. a region of positive electrostatic potential on the side of a atom opposite a sigma bond. Basis of halogen bonds and related stuff.
 * Thermally activated delayed fluorescence
 * Multicellular magnetotactic prokaryote(s). Multicellular bacteria. Eg. Candidatus Magnetoglobus multicellularis.
 * Deformation density, the actual electron density minus what the electron density would be if the atoms didn't interact.

Different pages for the chemistry of some elements in each of its major oxidation states
Such as Copper(II), Copper(I), Iron(II), Iron(III), Manganese(II), Magnanese(IV), etcetera

Draft starter
Makes drafts with a chembox and a few headings in my namespace (for my use only, if anyone else uses it, I'll move the page(s) to their user namespace)

potential properties to be added to the chembox template

 * Critical pressure and Critical temperature - are important properties of gases and some liquids (of stuff stored under pressure) because it dictates the storage conditions among other reasons. Fairly simple to implement.
 * Dielectric constant - not sure how to implement because despite its name it isn't constant and varies with frequency (it varies with some other factors as well, but I think they're all covered under STP)

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