User:Tamara Omar/Chromite

Health and Environmental Impacts
The increased use of chromium in anthropogenic processes in the past decades is developing major health and environmental concerns around the world. When chromium is in the trivalent (Cr(III)) form, it is a crucial part of a balanced animal and human diet. However, its defect will cause a disruption to the lipids and glucose metabolism in animals and humans. On the other hand, when chromium is in its hexavalent (Cr(VI)) form, it is a highly toxic carcinogen and if ingested by an animal or human it may cause death.

Health effects

When chromite ore is mined, it is aimed for the production of ferrochrome and produces a chromite concentrate of a high chromium to iron ratio. It can also be crushed and processed. Chromite concentrate, when combined with a reductant such as coal or coke and a high temperature furnace can produce ferrochrome. Ferrochrome is a type of ferroalloy that is an alloy in between chromium and iron. This ferroalloy, as well as chromite concentrate can introduce various health effects. Introducing a definitive control approach and distinct mitigation techniques can provide importance related to the safety of human health.

When chromite ore is exposed to surface conditions, weathering and oxidation can occur. The element chromium is most abundant in chromite in the form of trivalent (Cr-III). When chromite ore is exposed to aboveground conditions, Cr-III can be converted to Cr-VI, which is the hexavalent state of chromium. Cr-VI is produced from Cr-III by means of dry milling or grinding of the ore. This is due to the moistness of the milling process as well as the atmosphere in which the milling is taking place. A wet environment and a non-oxygenated atmosphere are ideal conditions to produce less Cr-VI, while the opposite is known to create more Cr-VI.

Production of Ferrochrome is observed to emit pollutants into the air such as nitrogen oxides, carbon oxides and sulfur oxides, as well as dust particulates with a high concentration of heavy metals such as chromium, zinc, lead, nickel and cadmium. During high temperature smelting of chromite ore to produce Ferrochrome, Cr-III is converted to Cr-VI. As with chromite ore, Ferrochrome is milled and therefore produces Cr-VI. Cr-VI is therefore introduced into the dust when the Ferrochrome is produced. This introduces health risks such as inhalation potential and leaching of toxins into the environment. Human exposure to chromium is ingestion, skin contact, and inhalation. Chromium-III and VI will accumulate in the tissues of humans and animals. The excretion of this type of chromium from the body tends to be very slow which means that elevated concentrations of chromium can be seen decades later in human tissues.

Environmental effects

Chromite mining, chromium, and ferrochome production can toxically effect the environment. Chromite mining is necessary when it comes to the production of economic commodities.

As a result of leaching of soils and the explicit discharge from industrial activities, weathering of rocks that contain chromium will enter the water column. The route of chromium uptake in plants is still ambiguous, but because it is a nonessential element, chromium will not have a distinct mechanism for that uptake which is independent from chromium speciation. Plant studies have shown that toxic effects on plants from chromium include things such as wilting, narrow leaves, delayed or reduced growth, a decrease in chlorophyll production, damage to root membranes, small root systems, death and many more. Chromium's structure is similar to other essential elements which means that it can impact the mineral nutrition of plants.

During industrial activities and production things such as sediment, water, soil, and air all become polluted and contaminated with chromium. Hexavalent chromium has negative impacts towards soil ecology because it decreases soil micro-organism presence, function, and diversity. Chromium concentrations in soil diversify depending on the different compositions of the sediments and rocks that the soil is made from. The chromium present in soil is a mixture of both Cr(VI) and Cr(III). Certain types of chromium such as Chromium-VI has the capability to pass into the cells of organisms. Dust particles from industry operations and industrial wastewater contaminate and pollute surface water, groundwater, and soils.

In aquatic environments, chromium could experience things such as dissolution, sorption, precipitation, oxidation, reduction, and desorption. In aquatic ecosystems chromium bioaccumulates in invertebrates, aquatic plants, fish, and algae. These toxic effects will operate differently because things such as sex, size, and the development stage of an organism may vary. Things such as the temperature of the water, its alkalinity, salinity, pH, and other contaminants will also impact these toxic effects on organisms.

Toxicology tests done in labs on rats and mice provides information on the doses of chromium in food or water which produces health problems in mammals such as reproductive harm, reduced growth and survival, behavioural changes, and cancer.