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Dolphus Edward Milligan was born in Brighton Alabama on June 17 1928. He received his bachelor’s degree in chemistry from Morehouse College in Atlanta in 1949. He earned a Master of Science (M.S) from Atlanta University in 1951. He then accepted a position as a chemistry instructor in Fort Valley State College in Georgia. He joined the faculty at the University of California at Berkeley while pursuing his doctorate studies. In 1996, When Robert F. Curl accepted the Nobel Prize in chemistry he expressed his appreciation for Milligan’s help on his earlier more volatile experiments. Milligan obtained his Ph.D in chemistry in 1958, his research focused on spectroscopic study of reaction intermediates at extremely low temperature. After completing this doctorate he joined the Melton Institute of industrial research in Pittsburg where he conducted basic research. In 1963, he joined the National Bureau of Standards as a physical chemist. In 1970, he became an adjunct professor at Howard University while retaining his position at Mellon. In 1971, he became the chief of the photochemistry section of the National Bureau of Standards. His work on Free radical research earned him the Arturo Miolati Prize for Free radical research from the University of Padua in Italy in 1965. He received the Washington academy of sciences award in physical science in 1968. In 1970, the U.S department of commerce awarded him the Gold medal for distinguished service. Milligan was a member of both the American Chemical Society (ACS) and the American Physical Society. On October 18th 1973 died suddenly in his office as the chief of the photochemistry section at the National Bureau of Standards. Few days earlier, he had learned that his research on the spectra of molecular ions were being recognized by the Samuel W. Stratton award, the highest honor conferred by the National Bureau of Standard. A scholarship fund was established at Morehouse College in his memory in 1974. In 2003, the University of Maryland, College Park established a fellowship in his honor in Collaboration with the National Institute of Standard and Technology.