User talk:Smokefoot

For older material, see
 * User talk:Smokefoot/TalkArch1
 * User talk:Smokefoot/TalkArch2
 * User talk:Smokefoot/TalkArch3
 * User talk:Smokefoot/TalkArch2009
 * User talk:Smokefoot/TalkArch2010
 * User talk:Smokefoot/TalkArch2011
 * User talk:Smokefoot/TalkArch2012
 * User talk:Smokefoot/TalkArch2013
 * User talk:Smokefoot/TalkArch2014
 * User talk:Smokefoot/TalkArch2015
 * User talk:Smokefoot/TalkArch2016
 * User talk:Smokefoot/TalkArch2017
 * User talk:Smokefoot/TalkArch2018
 * User talk:Smokefoot/TalkArch2019
 * User talk:Smokefoot/TalkArch2020
 * User talk:Smokefoot/TalkArch2021
 * User talk:Smokefoot/TalkArch2022
 * User talk:Smokefoot/TalkArch2023

CS1 error on 1-Pentyne
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=1-Pentyne&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1193804586%7C1-Pentyne%5D%5D Ask for help])

CS1 error on Methyl group
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Methyl_group&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1194042663%7CMethyl%20group%5D%5D Ask for help])

CS1 error on Hydrogen bond
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Hydrogen_bond&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1197448822%7CHydrogen%20bond%5D%5D Ask for help])

CS1 error on Phosphoric acid
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 * A "bare URL and missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Phosphoric_acid&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1201029112%7CPhosphoric%20acid%5D%5D Ask for help])

CS1 error on Starch
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Starch&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1202390596%7CStarch%5D%5D Ask for help])

CS1 error on Lanthanum acetylacetonate
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Lanthanum_acetylacetonate&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1202834754%7CLanthanum%20acetylacetonate%5D%5D Ask for help])

CS1 error on Europium acetylacetonate
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Europium_acetylacetonate&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1203272475%7CEuropium%20acetylacetonate%5D%5D Ask for help])

CS1 error on Gadolinium acetylacetonate
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Gadolinium_acetylacetonate&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1203304260%7CGadolinium%20acetylacetonate%5D%5D Ask for help])

CS1 error on Samarium(III) acetylacetonate
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Samarium(III)_acetylacetonate&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1203322006%7CSamarium(III)%20acetylacetonate%5D%5D Ask for help])

CS1 error on Samarium(III) acetylacetonate
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Samarium(III)_acetylacetonate&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1203814470%7CSamarium(III)%20acetylacetonate%5D%5D Ask for help])

CS1 error on Thulium acetylacetonate
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Thulium_acetylacetonate&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1203859569%7CThulium%20acetylacetonate%5D%5D Ask for help])

CS1 error on Terbium acetylacetonate
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Terbium_acetylacetonate&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1203888298%7CTerbium%20acetylacetonate%5D%5D Ask for help])

List of colleges and universities in the United States by endowment
The last edit states, "New York is one of the few populous states without a public university with a large endowment." The statement is only correct in the context of the NACUBO list, and it ignores State University of New York as written.

While the statement on smaller populations is true, my minor concern is the subtle implication of a conclusion not stated by a cited source. With that said, the entire paragraph could probably benefit from another citation or two. Redraiderengineer (talk) 18:02, 6 February 2024 (UTC) I was intrigued by the earlier request for a RS, but it seems that the information provided by my addition is common knowledge, WP:CK. So what would one cite, a source for the populations of these states? As for New York state having few well-endowed public universities, that info is provided by NACUBO, and their data are reproduced in the table. Let me know what you think. --Smokefoot (talk) 18:25, 6 February 2024 (UTC)

CS1 error on Triphenylbismuth
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CS1 error on Naphthenic acid
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CS1 error on Urushibara nickel
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CS1 error on Isopropylmagnesium chloride
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 * A "missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Isopropylmagnesium_chloride&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1207382311%7CIsopropylmagnesium%20chloride%5D%5D Ask for help])

CS1 error on Ethylene
Hello, I'm Qwerfjkl (bot). I have automatically detected that this edit performed by you, on the page Ethylene, may have introduced referencing errors. They are as follows: Please check this page and fix the errors highlighted. If you think this is a false positive, you can [//en.wikipedia.org/w/index.php?action=edit&preload=User:Qwerfjkl/Botpreload&editintro=User:Qwerfjkl/boteditintro&minor=&title=User_talk:Qwerfjkl&preloadtitle=Qwerfjkl%20(bot)%20–%20Smokefoot&section=new&preloadparams%5b%5d=&preloadparams%5b%5d=1208448634 report it to my operator]. Thanks, Qwerfjkl (bot) (talk) 15:39, 17 February 2024 (UTC)
 * A "bare URL and missing title" error. References show this error when they do not have a title. Please edit the article to add the appropriate title parameter to the reference. ([//en.wikipedia.org/w/index.php?title=Ethylene&action=edit&minor=minor&summary=Fixing+reference+error+raised+by+%5B%5BUser%3AQwerfjkl%20(bot)%7CQwerfjkl%20(bot)%5D%5D Fix] | [//en.wikipedia.org/w/index.php?title=Wikipedia:Help_desk&action=edit&section=new&preload=User:Qwerfjkl%20(bot)/helpform&preloadtitle=Referencing%20errors%20on%20%5B%5BSpecial%3ADiff%2F1208448634%7CEthylene%5D%5D Ask for help])

Invitation to join New pages patrol
Hello Smokefoot! Thank you for your consideration. We hope to see you around! MediaWiki message delivery (talk) 15:21, 22 February 2024 (UTC)
 * The New Pages Patrol is currently struggling to keep up with the influx of new articles needing review. We could use a few extra hands to help.
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CS1 error on Kavalactone
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CS1 error on Artificial photosynthesis
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Nitrilotris(methylenephosphonic acid
Hello Smokefoot; I was passing by this redirect that did not look wholly correct to me, and wanted to ask whether the missing closing bracket on this redirect was intentional? No redirect currently exists with the closing-parenthesis, so this could possibly be moved there if that was the intention. Thanks, Utopes (talk / cont) 14:37, 1 March 2024 (UTC)
 * Thank you for catching that issue. It has been repaired.  --Smokefoot (talk) 14:21, 2 March 2024 (UTC)

"Nitrilotris(methylenephosphonic acid" listed at Redirects for discussion
The redirect [//en.wikipedia.org/w/index.php?title=Nitrilotris(methylenephosphonic_acid&redirect=no Nitrilotris(methylenephosphonic acid] has been listed at redirects for discussion to determine whether its use and function meets the redirect guidelines. Anyone, including you, is welcome to comment on this redirect at  until a consensus is reached. Utopes (talk / cont) 17:46, 3 March 2024 (UTC)

Chlorosalicylic acid
I'm deeply disappointed that you created Chlorosalicylic acid but did not fully develop the topic. As you know, the main namespace is not for drafts. You could have used a user sandbox for this. Wikipedia is not the wild west that it might have been twenty years ago. Chris Troutman ( talk )  19:20, 10 March 2024 (UTC)

Like recent specialized publications on topics one doesnt understand? Try these on
See User talk:Jwdietrich2 for details. Jwdietrich2 (talk) 20:50, 23 March 2024 (UTC)

Edit summaries
Thanks for your addition to Isononyl alcohol, but please be careful not to use a misleading edit summary. Your summary referred only to changing a reference. Pam D  04:23, 4 April 2024 (UTC)

Cobalt(II) chlorate image
Yikes, that was indeed poor. I removed it from other-languages' Wikipedia articles, and it will be deleted altogether off Commons next week. DMacks (talk) 20:27, 6 April 2024 (UTC)

Manganese compound
Smokefoot, i replied to your recent post on Talk:Pentacarbonylhydridomanganese. Solomonfromfinland (talk) 18:28, 9 April 2024 (UTC)

Thiazolone moved to draftspace
Thanks for your contributions to Thiazolone. Unfortunately, I do not think it is ready for publishing at this time because it has no sources. I have converted your article to a draft which you can improve, undisturbed for a while.

Please see more information at Help:Unreviewed new page. When the article is ready for publication, please click on the "Submit your draft for review!" button at the top of the page OR move the page back. JoeNMLC (talk) 18:52, 18 April 2024 (UTC)

Titanocene dicarbonyl
Hi, I saw you reverted my addition of the factoid in Titanocene dicarbonyl. Of course, it is. But as the named elements were no links, the reason why the compounds are related remaines to the not to much fact based reader rather obscure. I changed the names of the elements into links. I hope the contribution now is able to please you. T.vanschaik (talk) 09:32, 30 April 2024 (UTC)
 * Thank you for your message. "Titanium is the lightest element in group 4, zirconium and hafnium are just heavier members there in." is just inappropriate.  Happy editing and keep up the good work. --Smokefoot (talk) 13:22, 30 April 2024 (UTC)

Your submission at Articles for creation: Thiazolone has been accepted
 Thiazolone, which you submitted to Articles for creation, has been created.

Congratulations, and thank you for helping expand the scope of Wikipedia! We hope you will continue making quality contributions.

Since you have made at least 10 edits over more than four days, you can now create articles yourself without posting a request. However, you may continue submitting work to Articles for creation if you prefer.

If you have any questions, you are welcome to ask at the  [//en.wikipedia.org/w/index.php?title=Wikipedia:WikiProject_Articles_for_creation/Help_desk/New_question&withJS=MediaWiki:AFCHD-wizard.js&page=Thiazolone help desk] . Once you have made at least 10 edits and had an account for at least four days, you will have the option to create articles yourself without posting a request to Articles for creation.

If you would like to help us improve this process, please consider.

Thanks again, and happy editing! asilvering (talk) 18:22, 6 May 2024 (UTC)

about Split proposal of Cytochrome P450
Maybe put CYPome as a separate page would be a good solution, referring to all CYP genes of a particular species or population? Meanwhile, P450-containing systems can be used to store more information about enzyme architecture and machinery and mechanism. Htmlzycq (talk) 08:11, 11 May 2024 (UTC)

Making Tetrachloroethylene a Good Article
Background: I mainly work on the Turkish Wikipedia, I have expanded the Turkish article for tetrachloroethylene (which is larger than twice of the English article in size) and nominated it as a Featured Article there. I plan to translate sections from that article to English and nominate the English article for Good Article status. It can require complete rewriting of sections but I don't it'll be an issue since I already have material to add. What do you think? ⲔⲖⲞⲢⲠⲒⲔⲢⲒⲚ (talk) 19:59, 16 May 2024 (UTC)
 * I will try to support your efforts. Here are my initial comments on the article:

--Smokefoot (talk) 20:39, 16 May 2024 (UTC)
 * It is (hopefully) not important to make the article long to make it FA.
 * Some editors attracted to the FA nomination will know little chemistry but such outsiders tend to be chemophobic (and chemo-ignorant). So, it will be important to document that it is not so awful. One of the main reasons that it is popular as cleaning agent is that it is nontoxic.  Unlike soap and classical detergents, TCE is mostly recycled.
 * Nonetheless, it could be useful to find info on biodegradation pathways and rates. I am sure that many dry cleaners dumped a lot of this stuff into the ground.
 * Although not combustible, we might look for its reactions upon incineration (inevitably HCl and CO2).
 * I will look for some chemistry (reactions) of this stuff.


 * You can check out the Turkish article via a translator program, it can give you an idea of what I've written. I did an extensive research on its history and old nomenclature.
 * In the TR article, I addressed the toxicity and possible carcinogenicity of PCE. I clarified the IARC classification with comparison to another materials classified 2A ("probably carcinogenic to humans") such as red meat and hot beverages (which the readers would be exposed on a nearly daily basis), so the readers can understand it better.
 * I added some information on its biodegradation, referred to pollution briefly.
 * I added the products of its pyrolysis and its other reactions there.

I will do the translation, but I might need help on formatting (esp. the citations).
 * ⲔⲖⲞⲢⲠⲒⲔⲢⲒⲚ (talk) 21:11, 16 May 2024 (UTC)

"Potassium heptafluoroniobate" listed at Redirects for discussion
The redirect [//en.wikipedia.org/w/index.php?title=Potassium_heptafluoroniobate&redirect=no Potassium heptafluoroniobate] has been listed at redirects for discussion to determine whether its use and function meets the redirect guidelines. Anyone, including you, is welcome to comment on this redirect at  until a consensus is reached. DMacks (talk) 15:13, 21 May 2024 (UTC)

CS1 error on Lidia Vallarino
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Nonmetal FAC #9
Good day Smookfoot. I know you're not a fan of this article as FA because you're not a fan of classifications within chemistry. That said, I'm asking all the folks who commented on FAC #8, and that includes you.

Are you able to comment on this nomination(?); there's no obligation. Regards, Sandbh (talk) 03:40, 29 May 2024 (UTC)

CS1 error on Alan S. Goldman
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Pidgeon process image
Hello Smokefoot. Can you comment on the mistaken inclusion of in the Pidgeon process article? I'm curious why would one associate Galvanic corrosion with a Magnesium process. Maybe you see an idea floating around in the aether that needs enunciation and then development. Cheers, Stickhandler (talk) 19:25, 11 June 2024 (UTC)

Azo, diazo?
Hey,

This is an old image of yours and it's currently states that the final compound is diazomethane - but it's showing the wrong structure, should be CH2 and a negative charge somewhere (carbon preferably). My old copy of March tells me that aliphatic diazonium compounds are highly unstable - though admittedly that is a relative concept in this instance.



. Project Osprey (talk) 00:00, 19 June 2024 (UTC)
 * Oh, I corrected the figure. Thank you very much, mate.  --Smokefoot (talk) 04:03, 19 June 2024 (UTC)
 * Apologies. The image was correct, it was the caption that was wrong. See this review Project Osprey (talk) 11:13, 21 June 2024 (UTC)
 * I'm a little surprised that methyldiazonium is such a weak acid, given how selective diazomethane is for being protonated by various acid groups and the usual route for lab-prep of diazomethane. DMacks (talk) 12:30, 21 June 2024 (UTC)
 * Although I have made diazomethane a couple of times, its chemistry always perplexed me. Apparently it can be lithiated.  And then there is tmsCHN2 which somehow gives the same products as diazomethane.  I guess that its ability to methylate involves protonation to give methyldiazonium?
 * I reverted the image so that it gives methyldiazonium. The JOC paper is useful.--Smokefoot (talk) 14:01, 21 June 2024 (UTC)
 * I once worked with a guy who developed an industrial process that used it. His OPR&D paper is in the diazomethane article (though not by my hand) - He had stories. Apparently the explosive limits reported in the literature varied too much for his liking, so he conducted his own studies at a multi-kilo scale (on a military site), so as to be sure. Made a big bang.
 * Single carbon compounds always seem to have anomalous properties, often usefully. The aqueous pKa of methanediazonium ([CH3N2]+) is estimated to be <10 so its not really acidic.
 * I don't really understand why you can't just make it in-situ the same way you make all the other diazo compounds: methylamine, nitrite and acid? Project Osprey (talk) 15:11, 21 June 2024 (UTC)
 * Regarding the TMS analog, our article does indeed note "When used as a reagent in organic synthesis to convert carboxylic acids to their methyl esters, trimethylsilyldiazomethane undergoes acid-catalysed methanolysis, forming diazomethane in situ.[8]". I think I only made diazomethane once, just cookbooking with Aldrich's kit to avoid boom. The Org. Synth. prep using diazald does mention several routes from methylamine. DMacks (talk) 17:05, 21 June 2024 (UTC)
 * Well, 10.1002/anie.200702131 provides an alternative TMSCHN2 mechanism. Someone should update our article:) DMacks (talk) 17:27, 21 June 2024 (UTC)
 * Did it. DMacks (talk) 18:11, 22 June 2024 (UTC)
 * So I turned methyldiazonium into a real article. DMacks (talk) 17:46, 21 June 2024 (UTC)

CS1 error on N-Methylformamide
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CS1 error on 2,3-Butanediamine
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Editor experience invitation
Hi Smokefoot :) I'm looking for experienced editors to interview here. Feel free to pass if you're not interested. Clovermoss 🍀  (talk) 17:31, 1 July 2024 (UTC)