Wedgwood scale

The Wedgwood scale (°W) is an obsolete temperature scale, which was used to measure temperatures above the boiling point of mercury of 356 C. The scale and associated measurement technique were proposed by the English potter Josiah Wedgwood in the 18th century. The measurement was based on the shrinking of clay when heated above red heat, and the shrinking was evaluated by comparing heated and unheated clay cylinders. It was the first standardised pyrometric device. The scale started at 1077.5 F being 0 °W and had 240 steps of 130 F-change. Both the origin and the step were later found inaccurate.

History
The boiling point of mercury limits the mercury-in-glass thermometer to temperatures below 356 °C, which is too low for many industrial applications such as pottery, glass making and metallurgy.

To solve this problem, n 1782, Wedgwood created an accurately scaled pyrometric device, with details published in the Philosophical Transactions of the Royal Society of London in 1782 (Vol. LXXII, part 2). This led him to be elected a fellow of the Royal Society.

Method
A 0.5-inch-diameter cylinder made from pipe clay was dried at the temperature of boiling water. This would prepare it for heating in the oven in which the temperature was to be measured. During the annealing, sintering (merging) of fine particles resulted in contraction of clay. After cooling, the temperature was evaluated from the diameter difference before and after heating assuming that the contraction is linear with temperature.

To facilitate the temperature calculation, Wedgwood built a device which would directly read the temperature. Two metal bars with scales on them were fixed one above another on a metal plate and inclined at a small angle. The spacing between the bars was 0.5 inches at one end and 0.3 inches at the lower end. The scale was divided into 240 equidistant parts. The unheated piece of clay would fit the 0.5-inch gap giving the zero temperature reading. After annealing, the clay cylinder would shrink and fit somewhere in between the left and right ends of the bars, and the temperature could be read from the scales on the bars.

Scale
The origin on the Wedgwood scale (0 °W) was set at the onset temperature of red heat, 1077.5 F. The scale had 240 steps of 130 F-change and extended up to 32277 F. Wedgwood tried to compare his scale with other scales by measuring the expansion of silver as a function of temperature. He also determined the melting points of three metals, namely copper (27 °W or 4587 F), silver (28 °W or 4717 F) and gold (32 °W or 5237 F). All these values are at least 2500 F-change too high.

Corrections
Louis-Bernard Guyton de Morveau used his pyrometer to evaluate the temperature scale of Wedgwood and came to the conclusion that the starting point should be significantly lower, at 517 F instead of 1077.5 F, and that the steps should be nearly halved from 130 F-change to no more than 62.5 F-change. However, even after this revision the Wedgwood measurements overestimated the melting points of elements.