Zelinsky-Kummant gas mask

The Zelinsky-Kummant gas mask is the world's first gas mask with the ability to absorb a wide range of chemical warfare agents. The gas mask was developed in 1915 by Russian chemist Nikolay Zelinsky and technologist of the Triangle plant M.I. Kummant. The design was later improved by I. D. Avalov and entered mass production. After adoption by the Imperial Russian Army during World War I, casualties from chemical attacks decreased sharply.

History
Early protection from chemical weapons were "wet masks," which were bandages soaked in a solution of hyposulfite, sodium phenolate, methenamine, etc. They functioned based on the chemical binding of toxic substances and were widely used on the fronts of World War I. However, in addition to the obvious difficulties with use in combat conditions, they only helped against a narrow range of gases (of which several dozen were already in use by 1915). Therefore, chemists searched for nonspecific adsorbents with the greatest absorption capacity. The Germans used diatomaceous earth with pumice, while specialists from the Mining Institute used a mixture of slaked lime and caustic soda lime. After numerous experiments, Nikolay Zelinsky suggested activated birch or linden charcoal.

By summer of 1916, several hundred thousand soldiers were fumigated, and in total the army received 5,030,660 gas masks. Since spring 1917, gas masks were no longer issued to combat units. Troops continued to suffer significant losses from chemical weapons: units on the front line received gas masks without a supply, and fresh reinforcements to the unit were not provided with RPE.

Flaws
The activated carbon filter perfectly absorbed chlorine at a relatively low concentration. Later, shells and mines were used for chemical attacks; and they were equipped with phosgene, hydrocyanic acid, and other toxic substances. This increased the concentration of toxic substances and changed their chemical composition; and it turned out that in the new conditions, activated carbon alone does not provide the required duration of protection. For example, at a phosgene concentration of 1%, filters began to pass it in less than 6 minutes - while an English filter (with the addition of soda lime with potassium permanganate, in addition to activated carbon) could absorb 5 times more phosgene. Similarly, at a hydrocyanic acid concentration of 0.1%, the service life of Zelinsky filters with activated carbon alone was nine minutes, and with the addition of a chemical absorber took one hour and five minutes. By 1918, English, French, American and German gas mask filters were filled with both activated carbon and chemical absorbers, but in Russia until the very end of the war, they continued to believe in the universality of activated carbon, contrary to the proposals of the Gas Prevention Laboratory of the Chemical Committee at G.A.U. In modern industrial gas masks, activated carbon can be saturated with various additives, that is, additives and chemicals are also used.

Substances in the form of aerosols such as fine dust and fog, began to be used for chemical attacks. Small particles passed between large pieces of activated carbon (4–11 mm) unhindered, and there were no aerosol filters in the gas mask boxes.

Another disadvantage of gas masks was difficulty breathing. Some soldiers took off their gas masks, and were poisoned. Some soldiers "fell out of action due to shortness of breath, palpitations, dizziness" to the point of loss of consciousness. This was initially attributed to increased respiratory resistance. Accordingly, they began to change the design of the filter. But even when the amount of absorber was reduced to such a small value that the service life turned out to be unacceptably short, the problem could not be solved. Then measurements showed that exhaled air, with an increased concentration of carbon dioxide and a reduced concentration of oxygen (up to 13%), accumulates in the mask and filter - and is then inhaled again. As a result, its concentration in the inhaled air could reach 5.5% (for comparison, the maximum permissible concentration of CO2: average over 8 hours - 0.5% (average shift); average over 15 minutes (maximum single) - 1.4%; t .e. 9 and 27 grams per 1 cubic meter, respectively). After modifications, the gas mask was equipped with exhalation and inhalation valves, and the concentration of carbon dioxide decreased (to approximately 1.3-3.6%, depending on the gas mask model and type of activity). Even after the alterations, the concentration of oxygen in the inhaled air was reduced, and carbon dioxide was increased.

Tests proved it was not always possible to achieve a hermetically sealed connection between the glass and the mask.

Users

 * : Inherited stocks from the Imperial Russian Army. Used during the Winter War.
 * : Received masks as wartime ally.
 * Russian Empire: Primary user.
 * : Inherited stocks from the Imperial Russian Army following World War I.
 * : Inherited stocks from the Imperial Russian Army following World War I.

Literature

 * Описание противогазных повязок и масок, имеющихся в действующих армиях. Смоленск, 1915.
 * Кориц И. Г. Удушливые и ядовитые газы Издание Штаба Московского военного округа. Москва, 1916.
 * (Ядовитые газы. Казань, 1917.)
 * Зелинский А. Н. Спаси и сохрани: К 100-летию «Противогаза Зелинского» // «Русский вестник». — 03.07.2015.
 * Супотницкий М. В., Петров С. В., Ковтун В. А., Борисов Ю. И. О приоритете российских ученых в создании современного фильтрующего противогаза: К 100-летию противогаза Зелинского—Кумманта // Российский химический журнал. — 2016. — No. 2. — С. 95–112.
 * Супотницкий М. В. [cont.ws/@lexa2/543706 От «шлема Гипо» — к защите Зелинского: Как совершенствовались противогазы в годы Первой мировой войны] // Офицеры. — 2011. — No. 1 (51). — С. 50–55.
 * Бакин А. Н., Рогожкин Ю. А., Горошинкин М. В. «С моим противогазом не бойтесь! Он спасет вас от любых газов». К 100-летию создания первого русского противогаза. // Военно-исторический журнал. — 2015. — No. 12. — С.41-45.