Polynitrides

Add links
From Wikipedia, the free encyclopedia

Polynitrides are solid chemical compounds with a large amount of nitrogen, beyond what would be expected from valencies. Some with N2 ions are termed pernitrides. Azides are not considered polynitrides, although pentazolates are.

They are formed at high pressures and mostly at high temperature.[1] But some are stable when decompressed to standard conditions. They are high energy materials, capable of exploding with high power. Some are very hard, almost as strong as diamond.[2]

List[edit]

formula crystal space group unit cell volume density at

pressure

comment reference
LiN Cmcm a = 3.819 b = 6.471 c = 3.446 78.6 [3]
LiN2 hexagonal P63/mmc a =2.631 c = 7.615 21.2 white [3]
LiN5 P2 [3]
BeN4 triclinic P1 a=2.4062 b=3.5119 c=3.506 α=104.29° β=111.39° γ=96.71° 85 GPa [4]
BeN4 monoclinic P21/c a=3.283 b=3.276 c=4.818 β=99.67° 1 bar 1D-chain [4]
Na3N8 tetragonal I41/amd a=4.9597 c=16.29 Z=4 400.7 [5]
NaN2 tetragonal P4/mmm a=3.001 c=4.101 Z=1 36.93 [5]
Mg2N4 [6]
MgN4 triclinic P1 a=3.58 b= 3.70 c=5.01 α=94.2° β=111.2° γ=71.6° 58.7 @108 GPa >50 GPa chains [6][7]
K9N56 orthorhombic Ibam a=5.2380 b=34.560 c=23.205 Z=8 61 GPa [8]
TiN2 tetragonal I4/mcm a=4.322 c=5.269 [9]
VN2 tetragonal I4/mcm a=4.3015 c=4.9827 Z=4 92.195 5.6883 73.3 bulk modulus 347 GPa [10]
FeN2 orthorhombic Pnnm a=4.431 b=3.722 c=2.421 Z=2 39.93 58.5 [11]
FeN4 triclinic a=2.5089 b=3.524 c=3.5409 105.08 110.26 92.03 Z=1 28.09 106 [11]
CoN2 orthorhombic Pnnm 31 GPa bulk modulus 216 GPa [12]
ZnN4 orthorhombic Ibam 14-130 GPa 1D-chain [1]
YN6 100 GPa N189+ rings [13]
Y2N11 100 GPa N-double helix [13]
Y5N14 tetragonal P4/mbm a=8.451 c=4.7316 Z=2 337.93 6.296 50 [14]
RuN2 orthorhombic Pnnm [15]
RhN2 orthorhombic Pnnm bulk modulus 235 GPa [16]
PdN2 Pa3 [17]
CsN5 Pbca penazolate [18]
CsN5 triclinic P1 [18]
CeN4 I41/a a=6.711 c=2.879 chains [19]
CeN6 R3m a=5.890 c=4.108 hexazine [19]
CeN14 hexagonal P6mm a =5.748 c =2.447 sheet [19]
CeN17 hexagonal P6mm a=6.111 c=2.842 sheet [19]
ReN2 monoclinic P21/c a=3.625 b=6.407 c=4.948 β=111.48° 0 hard; bulk modulus 330 GPa; N24− & N3− [20]
OsN2 orthorhombic Pnnm bulk modulus 358 GPa [2]
IrN2 monoclinic P21/c bulk modulus 428 GPa [21][2]
PtN2 Pa3 bulk modulus 372 GPa [22]

References[edit]

  1. ^ a b Zhang, Yuchen; Huang, Xiaoli; Yao, Yansun; Zhang, Zihan; Tian, Fubo; Chen, Wuhao; Chen, Su; Jiang, Shuqing; Duan, Defang; Cui, Tian (2022-03-16). "Dirac nodal-line semimetal zinc polynitride at high pressure". Physical Review B. 105 (12): 125120. Bibcode:2022PhRvB.105l5120Z. doi:10.1103/PhysRevB.105.125120. ISSN 2469-9950. S2CID 247515712.
  2. ^ a b c Young, Andrea F.; Sanloup, Chrystele; Gregoryanz, Eugene; Scandolo, Sandro; Hemley, Russell J.; Mao, Ho-kwang (2006-04-20). "Synthesis of Novel Transition Metal Nitrides IrN 2 and OsN 2". Physical Review Letters. 96 (15): 155501. Bibcode:2006PhRvL..96o5501Y. doi:10.1103/PhysRevLett.96.155501. ISSN 0031-9007. PMID 16712167.
  3. ^ a b c Laniel, Dominique; Weck, Gunnar; Loubeyre, Paul (2018-09-04). "Direct Reaction of Nitrogen and Lithium up to 75 GPa: Synthesis of the Li 3 N, LiN, LiN 2 , and LiN 5 Compounds". Inorganic Chemistry. 57 (17): 10685–10693. doi:10.1021/acs.inorgchem.8b01325. ISSN 0020-1669. PMID 30137975. S2CID 52074339.
  4. ^ a b Bykov, Maxim; Fedotenko, Timofey; Chariton, Stella; Laniel, Dominique; Glazyrin, Konstantin; Hanfland, Michael; Smith, Jesse S.; Prakapenka, Vitali B.; Mahmood, Mohammad F.; Goncharov, Alexander F.; Ponomareva, Alena V.; Tasnádi, Ferenc; Abrikosov, Alexei I.; Bin Masood, Talha; Hotz, Ingrid (2021-04-26). "High-Pressure Synthesis of Dirac Materials: Layered van der Waals Bonded BeN 4 Polymorph". Physical Review Letters. 126 (17): 175501. arXiv:2010.15774. Bibcode:2021PhRvL.126q5501B. doi:10.1103/PhysRevLett.126.175501. ISSN 0031-9007. PMID 33988447. S2CID 227840429.
  5. ^ a b Bykov, Maxim; Tasca, Kelin R.; Batyrev, Iskander G.; Smith, Dean; Glazyrin, Konstantin; Chariton, Stella; Mahmood, Mohammad; Goncharov, Alexander F. (2020-10-19). "Dinitrogen as a Universal Electron Acceptor in Solid-State Chemistry: An Example of Uncommon Metallic Compounds Na 3 (N 2 ) 4 and NaN 2". Inorganic Chemistry. 59 (20): 14819–14826. doi:10.1021/acs.inorgchem.0c01863. ISSN 0020-1669. PMID 33000943. S2CID 222167549.
  6. ^ a b Laniel, Dominique; Winkler, Bjoern; Koemets, Egor; Fedotenko, Timofey; Bykov, Maxim; Bykova, Elena; Dubrovinsky, Leonid; Dubrovinskaia, Natalia (2019-10-04). "Synthesis of magnesium-nitrogen salts of polynitrogen anions". Nature Communications. 10 (1): 4515. Bibcode:2019NatCo..10.4515L. doi:10.1038/s41467-019-12530-w. ISSN 2041-1723. PMC 6778147. PMID 31586062.
  7. ^ Zhang, Yuchen; Zhang, Kexin; Yu, Jingkun; Liu, Zhengtao; Jiang, Shuqing; Duan, Defang; Huang, Xiaoli; Cui, Tian (2024-04-25). "One-Dimensional Non-coplanar Nitrogen Chains in Manganese Tetranitride under High Pressure". The Journal of Physical Chemistry Letters. 15 (16): 4256–4262. doi:10.1021/acs.jpclett.4c00861. ISSN 1948-7185.
  8. ^ Laniel, Dominique; Trybel, Florian; Yin, Yuqing; Fedotenko, Timofey; Khandarkhaeva, Saiana; Aslandukov, Andrey; Aprilis, Georgios; Abrikosov, Alexei I.; Bin Masood, Talha; Giacobbe, Carlotta; Bright, Eleanor Lawrence; Glazyrin, Konstantin; Hanfland, Michael; Wright, Jonathan; Hotz, Ingrid (May 2023). "Aromatic hexazine [N6]4− anion featured in the complex structure of the high-pressure potassium nitrogen compound K9N56". Nature Chemistry. 15 (5): 641–646. Bibcode:2023NatCh..15..641L. doi:10.1038/s41557-023-01148-7. ISSN 1755-4330. PMID 36879075. S2CID 257377020.
  9. ^ Bhadram, Venkata S.; Kim, Duck Young; Strobel, Timothy A. (2016-03-22). "High-Pressure Synthesis and Characterization of Incompressible Titanium Pernitride". Chemistry of Materials. 28 (6): 1616–1620. doi:10.1021/acs.chemmater.6b00042. ISSN 0897-4756. OSTI 1364642.
  10. ^ Asano, Shuto; Niwa, Ken; Sasaki, Takuya; Gaida, Nico Alexander; Hasegawa, Masashi (2022). "High pressure synthesis and the valence state of vanadium ions for the novel transition metal pernitride, CuAl 2 -type VN 2". Dalton Transactions. 51 (7): 2656–2659. doi:10.1039/D1DT04310B. ISSN 1477-9226. PMID 35106526. S2CID 246474984.
  11. ^ a b Bykov, M.; Bykova, E.; Aprilis, G.; Glazyrin, K.; Koemets, E.; Chuvashova, I.; Kupenko, I.; McCammon, C.; Mezouar, M.; Prakapenka, V.; Liermann, H.-P.; Tasnádi, F.; Ponomareva, A. V.; Abrikosov, I. A.; Dubrovinskaia, N. (2018-07-16). "Fe-N system at high pressure reveals a compound featuring polymeric nitrogen chains". Nature Communications. 9 (1): 2756. Bibcode:2018NatCo...9.2756B. doi:10.1038/s41467-018-05143-2. ISSN 2041-1723. PMC 6048061. PMID 30013071.
  12. ^ Niwa, Ken; Terabe, Toshiki; Kato, Daiki; Takayama, Shin; Kato, Masahiko; Soda, Kazuo; Hasegawa, Masashi (2017-06-05). "Highly Coordinated Iron and Cobalt Nitrides Synthesized at High Pressures and High Temperatures". Inorganic Chemistry. 56 (11): 6410–6418. doi:10.1021/acs.inorgchem.7b00516. ISSN 0020-1669. PMID 28509545.
  13. ^ a b Aslandukov, Andrey; Trybel, Florian; Aslandukova, Alena; Laniel, Dominique; Fedotenko, Timofey; Khandarkhaeva, Saiana; Aprilis, Georgios; Giacobbe, Carlotta; Lawrence Bright, Eleanor; Abrikosov, Igor A.; Dubrovinsky, Leonid; Dubrovinskaia, Natalia (2022-08-22). "Anionic N 18 Macrocycles and a Polynitrogen Double Helix in Novel Yttrium Polynitrides YN 6 and Y 2 N 11 at 100 GPa". Angewandte Chemie International Edition. 61 (34): e202207469. doi:10.1002/anie.202207469. ISSN 1433-7851. PMC 9546263. PMID 35726633.
  14. ^ Aslandukov, Andrey; Aslandukova, Alena; Laniel, Dominique; Koemets, Iuliia; Fedotenko, Timofey; Yuan, Liang; Steinle-Neumann, Gerd; Glazyrin, Konstantin; Hanfland, Michael; Dubrovinsky, Leonid; Dubrovinskaia, Natalia (2021-08-19). "High-Pressure Yttrium Nitride, Y 5 N 14 , Featuring Three Distinct Types of Nitrogen Dimers". The Journal of Physical Chemistry C. 125 (32): 18077–18084. doi:10.1021/acs.jpcc.1c06210. ISSN 1932-7447. S2CID 238715134.
  15. ^ Niwa, Ken; Suzuki, Kentaro; Muto, Shunsuke; Tatsumi, Kazuyoshi; Soda, Kazuo; Kikegawa, Takumi; Hasegawa, Masashi (2014-10-20). "Discovery of the Last Remaining Binary Platinum‐Group Pernitride RuN 2". Chemistry – A European Journal. 20 (43): 13885–13888. doi:10.1002/chem.201404165. ISSN 0947-6539. PMID 25205266.
  16. ^ Niwa, Ken; Dzivenko, Dmytro; Suzuki, Kentaro; Riedel, Ralf; Troyan, Ivan; Eremets, Mikhail; Hasegawa, Masashi (2014-01-21). "High Pressure Synthesis of Marcasite-Type Rhodium Pernitride". Inorganic Chemistry. 53 (2): 697–699. doi:10.1021/ic402885k. ISSN 0020-1669. PMID 24393052.
  17. ^ Crowhurst, Jonathan C.; Goncharov, Alexander F.; Sadigh, B.; Zaug, J.M.; Aberg, D.; Meng, Yue; Prakapenka, Vitali B. (January 2008). "Synthesis and characterization of nitrides of iridium and palladium". Journal of Materials Research. 23 (1): 1–5. Bibcode:2008JMatR..23....1C. doi:10.1557/JMR.2008.0027. ISSN 0884-2914. S2CID 98557681.
  18. ^ a b Steele, Brad A.; Stavrou, Elissaios; Crowhurst, Jonathan C.; Zaug, Joseph M.; Prakapenka, Vitali B.; Oleynik, Ivan I. (2017-01-24). "High-Pressure Synthesis of a Pentazolate Salt". Chemistry of Materials. 29 (2): 735–741. arXiv:1612.01918. doi:10.1021/acs.chemmater.6b04538. ISSN 0897-4756. S2CID 99194135.
  19. ^ a b c d Wang, Yuanyuan; Li, Zhihui; Li, Ruixin; Li, Yi; Liu, Shuang; Yao, Zhen; Liu, Bingbing (24 July 2023). "Two Ultrahigh-Energy-Density Layered Cerium Polynitrides with Molecular Sieve Channel". Inorganic Chemistry. 62 (29): 11674–11681. doi:10.1021/acs.inorgchem.3c01532. PMID 37417932. S2CID 259357919.
  20. ^ Bykov, Maxim; Chariton, Stella; Fei, Hongzhan; Fedotenko, Timofey; Aprilis, Georgios; Ponomareva, Alena V.; Tasnádi, Ferenc; Abrikosov, Igor A.; Merle, Benoit; Feldner, Patrick; Vogel, Sebastian; Schnick, Wolfgang; Prakapenka, Vitali B.; Greenberg, Eran; Hanfland, Michael (2019-07-05). "High-pressure synthesis of ultraincompressible hard rhenium nitride pernitride Re2(N2)(N)2 stable at ambient conditions". Nature Communications. 10 (1): 2994. arXiv:1902.09249. Bibcode:2019NatCo..10.2994B. doi:10.1038/s41467-019-10995-3. ISSN 2041-1723. PMC 6611777. PMID 31278267.
  21. ^ Crowhurst, Jonathan C.; Goncharov, Alexander F.; Sadigh, B.; Zaug, J.M.; Aberg, D.; Meng, Yue; Prakapenka, Vitali B. (January 2008). "Synthesis and characterization of nitrides of iridium and palladium". Journal of Materials Research. 23 (1): 1–5. Bibcode:2008JMatR..23....1C. doi:10.1557/JMR.2008.0027. ISSN 0884-2914. S2CID 98557681.
  22. ^ Crowhurst, Jonathan C.; Goncharov, Alexander F.; Sadigh, Babak; Evans, Cheryl L.; Morrall, Peter G.; Ferreira, James L.; Nelson, A. J. (2006-03-03). "Synthesis and Characterization of the Nitrides of Platinum and Iridium". Science. 311 (5765): 1275–1278. Bibcode:2006Sci...311.1275C. doi:10.1126/science.1121813. ISSN 0036-8075. PMID 16513980. S2CID 21440230.
Retrieved from "https://en.wikipedia.org/w/index.php?title=Polynitrides&oldid=1222829677"