Talk:Bis(cyclopentadienyl)titanium(III) chloride

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	This article was accepted from this draft on 22 April 2017 by reviewer Graeme Bartlett (talk · contribs).

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A fact from Bis(cyclopentadienyl)titanium(III) chloride appeared on Wikipedia's Main Page in the Did you know column on 6 July 2017 (check views). The text of the entry was as follows:

Did you know... that the Nugent–RajanBabu reagent can be used to prepare a key intermediate in the synthesis of vinorelbine, a treatment for non-small-cell lung cancer?

A record of the entry may be seen at Wikipedia:Recent additions/2017/July. The nomination discussion and review may be seen at Template:Did you know nominations/Bis(cyclopentadienyl)titanium(III) chloride.

Wikipedia

Free radical bit[edit]

Probably caution is warranted in playing up the free radical aspect. A useful term is "radical-behavior".--Smokefoot (talk) 05:53, 5 May 2017 (UTC)[reply]

I've been tidying up for the DYK, Smokefoot, but any tweaks / changes / additions / re-writes welcome. There is plenty that can be done to improve this. EdChem (talk) 13:34, 5 May 2017 (UTC)[reply]

Reduction Potential[edit]

Cp2TiCl is listed in the one-electron reductant category but no potential is given. Anyone know what it is? It's hard to find stuff like this for well-known old compounds. Pelirojopajaro (talk) 14:26, 5 April 2018 (UTC)[reply]

It is not a one-electron reductant in the sense of outer-sphere electron transfer, where redox potentials are readily obtainable. Instead the reagent participates in atom-transfer reaction but without releasing the species that is reduced. Furthermore "it" is a dimer, but the entity that participates in atom-trans is probably monomeric Cp₂TiCl. So the situation is complicated.--Smokefoot (talk) 18:52, 5 April 2018 (UTC)[reply]