Americium-241

Americium-241 (241Americium, Am-241) is an isotope of americium. Like all isotopes of americium, it is radioactive, with a half-life of $241.057$. 241Americium is the most common isotope of americium as well as the most prevalent isotope of americium in nuclear waste. It is commonly found in ionization type smoke detectors and is a potential fuel for long-lifetime radioisotope thermoelectric generators (RTGs). Its common parent nuclides are β− from 241plutonium, EC from 241curium, and α from 245Berkelium. 241Americium is not fissile, but is fissionable, and the critical mass of a bare sphere is 57.6 – and a sphere diameter of 19 –. Americium-241 has a specific activity of 3.43 Ci/g. It is commonly found in the form of americium-241 dioxide. This isotope also has one meta state, 241mamericium, with an excitation energy of 2.2 MeV and a half-life of $432.6 years$. The presence of americium-241 in plutonium is determined by the original concentration of plutonium-241 and the sample age. Because of the low penetration of alpha radiation, americium-241 only poses a health risk when ingested or inhaled. Older samples of plutonium containing 241plutonium contain a buildup of 241americium. A chemical removal of americium-241 from reworked plutonium (e.g., during reworking of plutonium pits) may be required in some cases.

Nucleosynthesis
Americium-241 has been produced in small quantities in nuclear reactors for decades, and many kilograms of 241Americium have been accumulated by now. Nevertheless, since it was first offered for sale in 1962, its price, about US$1,500 per gram of 241Americium, remains almost unchanged owing to the very complex separation procedure.

Americium-241 is not synthesized directly from uranium – the most common reactor material – but from the plutonium isotope 239plutonium. The latter needs to be produced first, according to the following nuclear process:


 * $$\mathrm{^{238}_{\ 92}U\ \xrightarrow {(n,\gamma)} \ ^{239}_{\ 92}U\ \xrightarrow [23.5 \ min]{\beta^-} \ ^{239}_{\ 93}Np\ \xrightarrow [2.3565 \ d]{\beta^-} \ ^{239}_{\ 94}Pu}$$

The capture of two neutrons by 239plutonium (a so-called (n,γ) reaction), followed by a β-decay, results in 241Americium:


 * $$\mathrm{^{239}_{\ 94}Pu\ \xrightarrow {2~(n,\gamma)} \ ^{241}_{\ 94}Pu\ \xrightarrow [14.35 \ yr]{\beta^-} \ ^{241}_{\ 95}Am}$$

The plutonium present in spent nuclear fuel contains about 12% of 241plutonium. Because it converts to 241Americium, 241plutonium can be extracted and may be used to generate further 241Americium. However, this process is rather slow: half of the original amount of 241plutonium decays to 241Americium after about 14 years, and the 241Americium amount reaches a maximum after 70 years.

The obtained 241Americium can be used for generating heavier americium isotopes by further neutron capture inside a nuclear reactor. In a light water reactor (LWR), 79% of neutron captures on 241Americium convert to 242Americium and 10% to its nuclear isomer 242mAmericium:


 * 79%:  $$\mathrm{^{241}_{\ 95}Am\ \xrightarrow {(n,\gamma)} \ ^{242}_{\ 95}Am}$$

Decay
Americium-241 decays mainly via alpha decay, with a weak gamma ray byproduct. The α-decay is shown as follows:

$$\mathrm{^{241\!\,}_{\ 95}Am\ \overset{432.2y}{\longrightarrow} \ ^{237}_{\ 93}Np~+~^{4}_{2}\alpha^{2+} +\gamma~59.5409~keV}$$

The α-decay energies are 5.486 MeV for 85% of the time (the one which is widely accepted for standard α-decay energy), 5.443 MeV for 13% of the time, and 5.388 MeV for the remaining 2%. The γ-ray energy is 59.5409 keV for the most part, with little amounts of other energies such as 13.9 keV, 17.8 keV and 26.4 keV.

The second most common type of decay that americium-241 undergoes is spontaneous fission, with a branching ratio of 3.6×10−12 and happening 1.2 times a second per gram of 241americium. It is written as such (the asterisk denotes an excited nucleus):

$$\mathrm{^{241}_{\ 95}Am\longrightarrow~^{241}_{\ 95}Am^*\longrightarrow3^1_0n~+~fission~products~+energy~(\gamma)} $$

The least common (rarest) type of decay for americium-241 is 34silicon cluster decay, with a branching ratio of less than 7.4×10−16. It is written as follows:

$$\mathrm{^{241\!\,}_{\ 95}Am\longrightarrow^{207}_{\ 81}Tl+^{34}_{14}Si}$$

Ionization-type smoke detector
Americium-241 is the only synthetic isotope to have found its way into the household, where the most common type of smoke detector (the ionization-type) uses (americium-241 dioxide) as its source of ionizing radiation. This isotope is preferred over 226radium because it emits 5times more alpha particles and relatively little harmful gamma radiation. With its half-life of $52,934.3$, the americium in a smoke detector decreases and includes about 3% neptunium after $7,543.28$, and about 5% after $432.2 years$. The amount of americium in a typical new smoke detector is 0.29 µg (about 1/3000 the weight of a small grain of sand) with an activity of 1 µCi. Some old industrial smoke detectors (notably from the Pyrotronics Corporation) can contain up to 80 μCi. The amount of 241americium declines slowly as it decays into neptunium-237 (237neptunium), a different transuranic element with a much longer half-life (about $1.23 μs$). The radiated alpha particles pass through an ionization chamber, an air-filled space between two electrodes, which allows a small, constant electric current to pass between the capacitor plates due to the radiation ionizing the air space between. Any smoke that enters the chamber blocks/absorbs some of the alpha particles from freely passing through and reduces the ionization and therefore causes a drop in the current. The alarm's circuitry detects this drop in the current and as a result, triggers the piezoelectric buzzer to sound. Compared to the alternative optical smoke detector, the ionization smoke detector is cheaper and can detect particles which are too small to produce significant light scattering. However, it is more prone to false alarms.

Manufacturing process
The process for making the americium used in the buttons on ionization-type smoke detectors begins with americium dioxide. The is thoroughly mixed with gold, shaped into a briquette, and fused by pressure and heat at over 1470 F. A backing of silver and a front covering of gold (or an alloy of gold or palladium) are applied to the briquette and sealed by hot forging. The briquette is then processed through several stages of cold rolling to achieve the desired thickness and levels of radiation emission. The final thickness is about 0.008 in, with the gold cover representing about one percent of the thickness. The resulting foil strip, which is about 0.8 in wide, is cut into sections 39 in long. The sources are punched out of the foil strip. Each disc, about 0.2 in in diameter, is mounted in a metal holder, usually made of aluminium. The holder is the housing, which is the majority of what is seen on the button. The thin rim on the holder is rolled over to completely seal the cut edge around the disc.

RTG (radioisotope thermoelectric generator) power generation
As 241Americium has a roughly similar half-life to 238plutonium (432.2 years vs. 87 years), it has been proposed as an active isotope of radioisotope thermoelectric generators, for use in spacecraft. Even though americium-241 produces less heat and electricity than plutonium-238 (the power yield is 114.7 mW/g for 241Americium vs. 570 mW/g for 238plutonium) and its radiation poses a greater threat to humans owing to gamma and neutron emission, it has advantages for long duration missions with its significantly longer half-life. The European Space Agency is working on RTGs based on americium-241 for its space probes as a result of the global shortage of plutonium-238 and easy access to americium-241 in Europe from nuclear waste reprocessing.

Its shielding requirements in an RTG are the second lowest of all possible isotopes: only 238plutonium requires less. An advantage over 238plutonium is that it is produced as nuclear waste and is nearly isotopically pure. Prototype designs of 241Americium RTGs expect 2–2.2 We/kg for 5–50 We RTGs design, putting 241Americium RTGs at parity with 238plutonium RTGs within that power range, as the vast majority of the mass of an RTG is not the isotopes, but the thermoelectrics, radiators, and isotope containment mass.

Neutron source
Oxides of 241americium pressed with beryllium can be very efficient neutron sources, since they emit alpha particles during radioactive decay:


 * $$\mathrm{^{241\!\,}_{\ 95}Am\ \overset{432.2y}{\longrightarrow} \ ^{237}_{\ 93}Np\ +\ ^{4}_{2}\alpha^{2+} +\ \gamma~59.5~keV}$$

Here americium acts as the alpha source, and beryllium produces neutrons owing to its large cross-section for the (α,n) nuclear reaction:
 * $\mathrm{^{9}_{4}Be\ +\ ^{4}_{2}\alpha^{2+} \longrightarrow \ ^{12}_{\ 6}C\ +\ ^{1}_{0}n\ +\ \gamma}$

The most widespread use of neutron sources is a neutron probe – a device used to measure the quantity of water present in soil, as well as moisture/density for quality control in highway construction. 241americium neutron sources are also used in well logging applications, as well as in neutron radiography, tomography, and other radiochemical investigations.

Production of other elements
Americium-241 is sometimes used as a starting material for the production of other transuranic elements and transactinides – for example, neutron bombardment of 241Americium yields 242Americium: $$\mathrm{^{241}_{\ 95}Am\ \xrightarrow {(n,\gamma)} \ ^{242}_{\ 95}Am}$$

From there, 82.7% of 242Americium decays to 242Curium and 17.3% to 242Plutonium:

82.7% → $$\mathrm{^{241}_{\ 95}Am\ \xrightarrow {(n,\gamma)} \ ^{242}_{\ 95}Am\ \xrightarrow [16.02 \ h]{\beta^-} \ ^{242}_{\ 96}Cm}$$

17.3%→ $$\mathrm{^{241}_{\ 95}Am\ \xrightarrow {(n,\gamma)} \ ^{242}_{\ 95}Am\ \xrightarrow [16.02 \ h]{\beta^+} \ ^{242}_{\ 94}Pu}$$

In the nuclear reactor, 242Americium is also up-converted by neutron capture to 243Americium and 244Americium, which transforms by β-decay to 242curium:
 * $$\mathrm{^{242}_{\ 95}Am\xrightarrow {(n,\gamma)}~^{243}_{\ 95}Am\ \xrightarrow {(n,\gamma)} \ ^{244}_{\ 95}Am\ \xrightarrow [10.1 \ h]{\beta^-} \ ^{244}_{\ 96}Cm}$$

Irradiation of 241Americium by 12carbon or 22Neon ions yields the isotopes 253einsteinium (einsteinium) or 263dubnium (dubnium), respectively. Furthermore, the element berkelium (243berkelium isotope) had been first intentionally produced and identified by bombarding 241Americium with alpha particles, in 1949, by the same Berkeley group, using the same 60 in cyclotron that had been used for many previous experiments.

Spectrometer
Americium-241 has been used as a portable source of both gamma rays and alpha particles for a number of medical and industrial uses. The 59.5409 keV gamma ray emissions from 241Americium in such sources can be used for indirect analysis of materials in radiography and X-ray fluorescence spectroscopy, as well as for quality control in fixed nuclear density gauges and nuclear densometers. For example, this isotope has been employed to gauge glass thickness to help create flat glass. Americium-241 is also suitable for calibration of gamma-ray spectrometers in the low-energy range, since its spectrum consists of nearly a single peak and negligible Compton continuum (at least three orders of magnitude lower intensity).

Medicine
Gamma rays from americium-241 have been used to provide passive diagnosis of thyroid function. This medical application is now obsolete. Americium-241's gamma rays can provide reasonable quality radiographs, with a 10-minute exposure time. 241americium radiographs have only been taken experimentally due to the long exposure time which increases the effective dose to living tissue. Reducing exposure duration reduces the chance of ionization events causing damage to cells and DNA, and is a critical component in the "time, distance, shielding" maxim used in radiation protection.

Hazards
Americium-241 has the same general hazards as other americium isotopes: it is both extremely toxic and radioactive. Although α-particles can be stopped by a sheet of paper, there are serious health concerns for ingestion of α-emitters. Americium and its isotopes are also very chemically toxic as well, in the form of heavy-metal toxicity. As little as 0.03 μCi is the maximum permissible body burden for 241americium.

Americium-241 is an α-emitter with a weak γ-ray byproduct. Safely handling americium-241 requires knowing and following proper safety precautions, as without them it would be extremely dangerous. Its specific gamma dose constant is 3.14 x 10−1 mR/hr/mCi or 8.48 x10−5 mSv/hr/MBq at 1 m.

If consumed, americium-241 is excreted within a few days and only 0.05% is absorbed in the blood. From there, roughly 45% of it goes to the liver and 45% to the bones, and the remaining 10% is excreted. The uptake to the liver depends on the individual and increases with age. In the bones, americium is first deposited over cortical and trabecular surfaces and slowly redistributes over the bone with time. The biological half-life of 241americium is $432.2 years$ in the bones and $19 years$ in the liver, whereas in the gonads (testicles and ovaries) it remains permanently; in all these organs, americium promotes formation of cancer cells as a result of its radioactivity.

Americium-241 often enters landfills from discarded smoke detectors. The rules associated with the disposal of smoke detectors are relaxed in most jurisdictions. In the U.S., the "Radioactive Boy Scout" David Hahn was able to concentrate americium-241 from smoke detectors after managing to buy a hundred of them at remainder prices and also stealing a few. There have been a few cases of exposure to americium-241, the worst case being that of Harold McCluskey who, at the age of 64, was exposed to 500 times the occupational standard for americium-241 as a result of an explosion in his lab. McCluskey died at the age of 75, not as a result of exposure, but of a heart disease which he had before the accident. Americium-241 has also been detected in the oceans as a result of nuclear weapons testing conducted by various nations.