Low-κ dielectric

In semiconductor manufacturing, a low-κ is a material with a small relative dielectric constant (κ, kappa) relative to silicon dioxide. Low-κ dielectric material implementation is one of several strategies used to allow continued scaling of microelectronic devices, colloquially referred to as extending Moore's law. In digital circuits, insulating dielectrics separate the conducting parts (wire interconnects and transistors) from one another. As components have scaled and transistors have gotten closer together, the insulating dielectrics have thinned to the point where charge build up and crosstalk adversely affect the performance of the device. Replacing the silicon dioxide with a low-κ dielectric of the same thickness reduces parasitic capacitance, enabling faster switching speeds (in case of synchronous circuits) and lower heat dissipation. In conversation such materials may be referred to as "low-k" (spoken "low-kay") rather than "low-κ" (low-kappa).

Low-κ materials
In integrated circuits, and CMOS devices, silicon dioxide can readily be formed on surfaces of Si through thermal oxidation, and can further be deposited on the surfaces of conductors using chemical vapor deposition or various other thin film fabrication methods. Due to the wide range of methods that can be used to cheaply form silicon dioxide layers, this material is used conventionally as the baseline to which other low permittivity dielectrics are compared. The relative dielectric constant of SiO2, the insulating material still used in silicon chips, is 3.9. This number is the ratio of the permittivity of SiO2 divided by permittivity of vacuum, εSiO 2 /ε0, where ε0 = 8.854×10−6 pF/μm. There are many materials with lower relative dielectric constants but few of them can be suitably integrated into a manufacturing process. Development efforts have focused primarily on the following classes of materials:

Fluorine-doped silicon dioxide
By doping SiO2 with fluorine to produce fluorinated silica glass, the relative dielectric constant is lowered from 3.9 to 3.5. Fluorine-doped oxide materials were used for the 180 nm and 130 nm technology nodes.

Organosilicate glass or OSG (Carbon-doped oxide or CDO)
By doping SiO2 with carbon, one can lower the relative dielectric constant to 3.0, the density to 1.4 g/cm3 and the thermal conductivity to 0.39 W/(m*K). The semiconductor industry has been using the organosilicate glass dielectrics since the 90 nm technology node.

Porous silicon dioxide
Various methods may be employed to create voids or pores in a silicon dioxide dielectric. Voids can have a relative dielectric constant of nearly 1, thus the dielectric constant of the porous material may be reduced by increasing the porosity of the film. Relative dielectric constants lower than 2.0 have been reported. Integration difficulties related to porous silicon dioxide implementation include low mechanical strength and difficult integration with etch and polish processes.

Porous organosilicate glass (carbon-doped oxide)
Porous organosilicate materials are usually obtained by a two-step procedure where the first step consists of the co-deposition of a labile organic phase (known as porogen) together with an organosilicate phase resulting in an organic-inorganic hybrid material. In the second step, the organic phase is decomposed by UV curing or annealing at a temperature of up to 400 °C, leaving behind pores in the organosilicate low-κ materials. Porous organosilicate glasses have been employed since the 45 nm technology node.

Spin-on organic polymeric dielectrics
Polymeric dielectrics are generally deposited by a spin-on approach, which is traditionally used for the deposition of photoresist materials, rather than chemical vapor deposition. Integration difficulties include low mechanical strength, coefficient of thermal expansion (CTE) mismatch and thermal stability. Some examples of spin-on organic low-κ polymers are polyimide, polynorbornenes, benzocyclobutene, and PTFE.

Spin-on silicon based polymeric dielectric
There are two kinds of silicon based polymeric dielectric materials, hydrogen silsesquioxane and methylsilsesquioxane.

Air gaps
The ultimate low-κ material is air with a relative permittivity value of ~1.0. However, the placement of air gaps between the conducting wires compromises the mechanical stability of the integrated circuit making it impractical to build an IC consisting entirely of air as the insulating material. Nevertheless, the strategic placement of air gaps can improve the chip's electrical performance without compromising critically its durability. For example, Intel uses air gaps for two interconnect levels in its 14 nm FinFET technology.