User:Graeme Bartlett/carbide oxide

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A carbide oxide or oxycarbide is a mixed anion compound that contains oxide (O2− or clusters) and carbon containing anions.

Oxycarbides are investigated for their catalytic activity.[1]

List[edit]

formula system space group unit cell Å volume density comment reference
Al2OC [2]
ScO0.39C0.56 [3]
ScC0.30O0.70 a=4.536 [3]
ScC0.56O0.08 a=4.6707 [3]
TiOC [4]
TiO0.5C0.5 electric conductor [5]
VO(0.52-0.46)C(0.23-0.37) [6]
Sr21Si2O6C6 cubic Fd3m a=1914.6 Z=8 7018 3.877 metallic brass [7]
Y2OC cubic [8]
ZrO0.31 C0.69 [9]
NbCxOy a=446.9 [1]
Mo2COx nanosheet [10]
not I4/mcm
HfOxCy [11]
UC0.4O0.6 electric conductor [12]
UCxO2-x [13]
UC1-xOx [13]
PuC0.5O0.3 film [14]

References[edit]

  1. ^ a b Kim, H. S.; Sayag, C.; Bugli, G.; Djega-Mariadassou, G.; Boudart, M. (1994). "Preparation, Characterization and Catalytic Activity of Niobium Oxynitride and Oxycarbide in Hydrotreatment". MRS Proceedings. 368. doi:10.1557/PROC-368-3. ISSN 0272-9172.
  2. ^ Nakashima, Yuki; Shirai, Takashi; Takai, Chika; Fuji, Masayoshi (2016). "Synthesis of aluminum oxycarbide (Al2OC) by selective microwave heating". Journal of the Ceramic Society of Japan. 124 (1): 122–124. doi:10.2109/jcersj2.15200. ISSN 1348-6535.
  3. ^ a b c Juarez-Arellano, Erick A.; Winkler, Björn; Bayarjargal, Lkhamsuren; Friedrich, Alexandra; Milman, Victor; Kammler, Daniel R.; Clark, Simon M.; Yan, Jinyuan; Koch-Müller, Monika; Schröder, Florian; Avalos-Borja, Miguel (2010-05). "Formation of scandium carbides and scandium oxycarbide from the elements at high-(P, T) conditions". Journal of Solid State Chemistry. 183 (5): 975–983. doi:10.1016/j.jssc.2010.02.019. {{cite journal}}: Check date values in: |date= (help)
  4. ^ Shakibi Nia, Niusha; Griesser, Christoph; Mairegger, Thomas; Wernig, Eva-Maria; Bernardi, Johannes; Portenkirchner, Engelbert; Penner, Simon; Kunze-Liebhäuser, Julia (2024-01-05). "Titanium Oxycarbide as Platinum-Free Electrocatalyst for Ethanol Oxidation". ACS Catalysis. 14 (1): 324–329. doi:10.1021/acscatal.3c04097. ISSN 2155-5435. PMC 10775143. PMID 38205023.{{cite journal}}: CS1 maint: PMC format (link)
  5. ^ Miller, David N.; Azad, Abdul K.; Delpouve, Heloise; Quazuguel, Lucille; Zhou, Jun; Sinha, Amit; Wormald, Philip; Irvine, John T. S. (2016). "Studies on the crystal structure, magnetic and conductivity properties of titanium oxycarbide solid solution (TiO 1−x C x )". Journal of Materials Chemistry A. 4 (15): 5730–5736. doi:10.1039/C6TA00042H. ISSN 2050-7488.
  6. ^ Bose, D. K.; Gupta, C. K. (1977-09). "An evaluation of vanadium oxycarbide as ladle addition to molten steels". Metallurgical Transactions B. 8 (3): 601–604. doi:10.1007/BF02658628. ISSN 0360-2141. {{cite journal}}: Check date values in: |date= (help)
  7. ^ Knoth, Markus; Rößler, Ute; Eisenmann, Brigitte (May 2005). "Zur Stabilisierung von Suboxidphasen durch Carbidionen: Die Kristallstruktur von Sr21Si2O5C6". Zeitschrift für anorganische und allgemeine Chemie. 631 (6–7): 1237–1240. doi:10.1002/zaac.200500023.
  8. ^ Holcombe, C. E.; Carpenter, D. A. (1981-05). "Identification of a New Yttrium Oxycarbide, Y 2 OC". Journal of the American Ceramic Society. 64 (5). doi:10.1111/j.1151-2916.1981.tb09592.x. ISSN 0002-7820. {{cite journal}}: Check date values in: |date= (help)
  9. ^ Shakibi Nia, Niusha; Hauser, Daniel; Schlicker, Lukas; Gili, Albert; Doran, Andrew; Gurlo, Aleksander; Penner, Simon; Kunze‐Liebhäuser, Julia (2019-11-19). "Zirconium Oxycarbide: A Highly Stable Catalyst Material for Electrochemical Energy Conversion". ChemPhysChem. 20 (22): 3067–3073. doi:10.1002/cphc.201900539. ISSN 1439-4235. PMC 6900196. PMID 31247128.{{cite journal}}: CS1 maint: PMC format (link)
  10. ^ Kurlov, Alexey; Deeva, Evgeniya B.; Abdala, Paula M.; Lebedev, Dmitry; Tsoukalou, Athanasia; Comas-Vives, Aleix; Fedorov, Alexey; Müller, Christoph R. (2020-10-02). "Exploiting two-dimensional morphology of molybdenum oxycarbide to enable efficient catalytic dry reforming of methane". Nature Communications. 11 (1). doi:10.1038/s41467-020-18721-0. ISSN 2041-1723. PMC 7532431. PMID 33009379.{{cite journal}}: CS1 maint: PMC format (link)
  11. ^ George, Mekha Raichie (2008-07-25). "Studies of ultra high temperature ceramic composite components: synthesis and characterization of HfOxCy and Si oxidation in atomic oxygen containing environments". {{cite journal}}: Cite journal requires |journal= (help)
  12. ^ Yang, Zhiqiang; Yang, Mingshuai; Shen, Zhenfang; Song, Wenchen; Li, Bin (2023-08-21). "Preparation and Electrochemical Dissolution of a Soluble Uranium Oxycarbide Anode". Inorganic Chemistry. 62 (33): 13512–13518. doi:10.1021/acs.inorgchem.3c01917. ISSN 0020-1669.
  13. ^ a b Cheik Njifon, I.; Torres, E. (2021-10). "Atomistic investigation of uranium oxycarbide (UCO) phase stability at finite temperatures: DFT+ U and AIMD+ U approaches". Journal of Nuclear Materials. 554: 153046. doi:10.1016/j.jnucmat.2021.153046. {{cite journal}}: Check date values in: |date= (help)
  14. ^ Roussel, Paul (2024-01-01). "Photoemission study of plutonium oxycarbide". Journal of Vacuum Science & Technology A. 42 (1). doi:10.1116/6.0003238. ISSN 0734-2101.